Technology Process of C26H46O3Si
There total 8 articles about C26H46O3Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 0.33 h / 50 °C
2: lithium chloride; lithium diisopropyl amide / tetrahydrofuran / 14 h / -78 - 20 °C
3: ammonia borane; lithium diisopropyl amide / tetrahydrofuran / 4 h / -78 - 20 °C
4: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 - 20 °C
5: diisobutylaluminium hydride / dichloromethane / 2 h / -40 - -10 °C
6: sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 1.5 h / 0 - 20 °C
7: sodium hexamethyldisilazane / tetrahydrofuran / 18 h / -78 - 20 °C
With
1H-imidazole; 2,6-dimethylpyridine; ammonia borane; iodine; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; diisobutylaluminium hydride; triphenylphosphine; lithium chloride; lithium diisopropyl amide;
In
tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
2: Myers alkylation reaction / 7: Wittig reaction;
DOI:10.1016/j.tetlet.2011.04.008
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 - 20 °C
2: diisobutylaluminium hydride / dichloromethane / 2 h / -40 - -10 °C
3: sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 1.5 h / 0 - 20 °C
4: sodium hexamethyldisilazane / tetrahydrofuran / 18 h / -78 - 20 °C
With
2,6-dimethylpyridine; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; diisobutylaluminium hydride;
In
tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
4: Wittig reaction;
DOI:10.1016/j.tetlet.2011.04.008