{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

Base Information

Chemical Name:{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol
CAS No.:171419-80-0
Molecular Formula:C₂₄H₃₄O₂Si
Molecular Weight:382.618
Hs Code.:

Synonyms:{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

Chemical Property:

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Technology Process of {2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

There total 15 articles about {2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 75-11-6
diiodomethane

: 171419-79-7
(R,E)-6-(tert-butyldiphenylsiloxy)-4-methylhex-2-en-1-ol

: 171419-80-0
{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

Guidance literature:: With diethylzinc; (4S,5S)-2-butyl-N⁴,N⁴,N⁵,N⁵-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide; In dichloromethane; Ambient temperature;
DOI:10.1016/00404-0399(50)1772A-

Reference yield:

: 171866-12-9
erythro-1,2,5-Trihydroxy-3-methyl-pentan

: 171419-80-0
{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

Guidance literature:: Multi-step reaction with 5 steps

1: Pb(OAc)4, K₂CO₃ / benzene / Ambient temperature

2: benzene / Ambient temperature

3: imidazole / dimethylformamide / Ambient temperature

4: diisobutylaluminum hydride / CH₂Cl₂ / -78 °C

5: 99 percent / (S,S)-(-)-N,N,N',N'-tetramethyltartaramide n-butylboron complex, Et₂Zn / CH₂Cl₂ / Ambient temperature

With 1H-imidazole; lead(IV) acetate; diethylzinc; diisobutylaluminium hydride; potassium carbonate; (4S,5S)-2-butyl-N⁴,N⁴,N⁵,N⁵-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide; In dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1016/00404-0399(50)1772A-

Reference yield:

: (2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-pentane-1,5-diol

: 171419-80-0
{2-[(R)-4-(tert-butyldiphenylsiloxy)butyl]-(1R,2S)-cyclopropyl}methanol

Guidance literature:: Multi-step reaction with 6 steps

1: 80percent AcOH / Ambient temperature

2: Pb(OAc)4, K₂CO₃ / benzene / Ambient temperature

3: benzene / Ambient temperature

4: imidazole / dimethylformamide / Ambient temperature

5: diisobutylaluminum hydride / CH₂Cl₂ / -78 °C

6: 99 percent / (S,S)-(-)-N,N,N',N'-tetramethyltartaramide n-butylboron complex, Et₂Zn / CH₂Cl₂ / Ambient temperature

With 1H-imidazole; lead(IV) acetate; diethylzinc; diisobutylaluminium hydride; potassium carbonate; acetic acid; (4S,5S)-2-butyl-N⁴,N⁴,N⁵,N⁵-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide; In dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1016/00404-0399(50)1772A-