tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron

Base Information

• Chemical Name: tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron
• CAS No.: 1585988-99-3
• Molecular Formula: C₄₈H₃₈FeO₄Si₂
• Molecular Weight: 790.845
• Mol file: 1585988-99-3.mol

Synonyms:tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron

Chemical Property of tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron

There total 1 articles about tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + 1,8-bis(triphenylsilyl)-1,7-octadiyne → tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienonyl)]iron (1585988-99-3)

Guidance literature:

With air; In toluene; at 140 ℃; for 48h; Schlenk technique;

DOI:10.1021/om5000562

Reference yield: 85.0%

tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienonyl)]iron (1585988-99-3) + acetonitrile (75-05-8,26809-02-9) → dicarbonylacetonitrile[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienyl)]iron (1585989-00-9)

Guidance literature:

tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η⁴-cyclopentadienonyl)]iron; acetonitrile; In toluene; at 5 ℃; for 48h; Irradiation; Schlenk technique; Inert atmosphere;

In toluene; at 5 - 20 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1021/om5000562

Reference yield:

tricarbonyl[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienonyl)]iron (1585988-99-3) + acetonitrile (75-05-8,26809-02-9) → dicarbonylacetonitrile[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienyl)]iron (1585989-00-9) + C50H44FeN2O2Si2

Guidance literature:

In toluene; at 5 ℃; for 48h; Irradiation; Schlenk technique; Inert atmosphere;

DOI:10.1021/om5000562

upstream raw materials:

iron pentacarbonyl

Downstream raw materials:

dicarbonylacetonitrile[2,5-bis(triphenylsilyl)-3,4-butylene-(η4-cyclopentadienyl)]iron