Magnesium;2,6-dimethyloctane;bromide

Base Information

• Chemical Name: Magnesium;2,6-dimethyloctane;bromide
• CAS No.: 114499-45-5
• Molecular Formula: C10H21BrMg
• Molecular Weight: 245.48
• DSSTox Substance ID: DTXSID00455495
• Mol file: 114499-45-5.mol

Synonyms:magnesium;2,6-dimethyloctane;bromide;DTXSID00455495;3 7-DIMETHYLOCTYLMAGNESIUM BROMIDE 1.0&;J-003101

Chemical Property of Magnesium;2,6-dimethyloctane;bromide

Chemical Property:

• Vapor Pressure: 3.21mmHg at 25°C
• Boiling Point: 159.7 °C at 760 mmHg
• Flash Point: 82.4 °C
• PSA: 0.00000
• Density: 0.856 g/mL at 25 °C
• LogP: 4.65210
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 244.06770
• Heavy Atom Count: 12
• Complexity: 64.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

3,7-Dimethyloctylmagnesium bromide solution 1.0M in diethyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+;Xn
• Hazard Codes: F+,Xn,C
• Statements: 12-19-22-66-67-34-14
• Safety Statements: 9-16-29-33-45-36/37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)CCCC(C)C[CH2-].[Mg+2].[Br-]

Technology Process of Magnesium;2,6-dimethyloctane;bromide

There total 5 articles about Magnesium;2,6-dimethyloctane;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

CuBr*(CH3)2 S + 3,7-dimethyloctylzinc chloride (133953-62-5) + 1-bromo-3,7-dimethyloctane (59965-20-7,72746-96-4,79434-89-2,3383-83-3) + (2E)-6-chloro-3,7-dimethyl-2,7-octadienyl acetate (74514-19-5) → 3,7-dimethyloctanyl-1-magnesium bromide (114499-45-5)

Guidance literature:

With ammonium chloride; Zinc chloride; In tetrahydrofuran; ice-water;

Reference yield:

3,7-dimethyloctylzinc chloride (133953-62-5) + 1-bromo-3,7-dimethyloctane (59965-20-7,72746-96-4,79434-89-2,3383-83-3) → 3,7-dimethyloctanyl-1-magnesium bromide (114499-45-5)

Guidance literature:

Zinc chloride; In tetrahydrofuran;

Reference yield:

CuBr*(CH3)2 S + 1-bromo-3,7-dimethyloctane (59965-20-7,72746-96-4,79434-89-2,3383-83-3) → 7,11,15-trimethyl-3-methylene-1,6-hexadecadiene + 3,7-dimethyloctanyl-1-magnesium bromide (114499-45-5)

Guidance literature:

In tetrahydrofuran;

upstream raw materials:

3,7-dimethyloctylzinc chloride

1-bromo-3,7-dimethyloctane

(2E)-6-chloro-3,7-dimethyl-2,7-octadienyl acetate

tetrahydrogeraniol

Downstream raw materials:

4,4'-bis(3,7-dimethyloctanyl)diphenylacetylene

4-(3,7-dimethyloctanyl)-trimethylsilylethinylbenzene

1,3-bis(4-(3,7-dimethyloctanyl)phenyl)-2-propanone ethylene acetal

4-(3',7'-dimethyloctanyl)phenylacetylene