Technology Process of C44H74O11Si
There total 21 articles about C44H74O11Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C28H52O7Si;
With
9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 4h;
Inert atmosphere;
C16H21IO4;
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate;
In
N,N-dimethyl-formamide;
stereoselective reaction;
Inert atmosphere;
DOI:10.1002/anie.201203406
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: ozone / dichloromethane / -78 °C
2.1: chromium dichloride / tetrahydrofuran / 2.33 h / 0 - 20 °C
3.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 4 h / -78 - 20 °C / Inert atmosphere
3.2: Inert atmosphere
With
chromium dichloride; ozone; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane;
2.1: |Takai-Utimoto Olefination / 3.2: |Suzuki-Miyaura Coupling;
DOI:10.1002/anie.201203406
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: diisobutylaluminium hydride / dichloromethane; hexane / -78 - 0 °C / Inert atmosphere
2.1: Jones reagent / acetone
3.1: diethyl ether / 1 h / 0 °C
4.1: ozone / dichloromethane / -78 °C
5.1: chromium dichloride / tetrahydrofuran / 2.33 h / 0 - 20 °C
6.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 4 h / -78 - 20 °C / Inert atmosphere
6.2: Inert atmosphere
With
chromium dichloride; Jones reagent; diisobutylaluminium hydride; ozone; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetone;
2.1: |Jones Oxidation / 5.1: |Takai-Utimoto Olefination / 6.2: |Suzuki-Miyaura Coupling;
DOI:10.1002/anie.201203406
