11-(p-tolyl)-11H-benzo[a]carbazole

Base Information

• Chemical Name: 11-(p-tolyl)-11H-benzo[a]carbazole
• CAS No.: 1392198-16-1
• Molecular Formula: C₂₃H₁₇N
• Molecular Weight: 307.395
• Mol file: 1392198-16-1.mol

Synonyms:11-(p-tolyl)-11H-benzo[a]carbazole

Chemical Property of 11-(p-tolyl)-11H-benzo[a]carbazole

Chemical Property:

Purity/Quality:

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Technology Process of 11-(p-tolyl)-11H-benzo[a]carbazole

There total 5 articles about 11-(p-tolyl)-11H-benzo[a]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.93%

benzo[b]naphtho[2,1-d]iodol-11-ium trifluoromethanesulfonate (1469876-15-0) + p-toluidine (106-49-0,12221-03-3) → 11-(p-tolyl)-11H-benzo[a]carbazole (1392198-16-1)

Guidance literature:

With copper diacetate; sodium carbonate; In ethylene glycol; isopropyl alcohol; at 90 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.ejmech.2013.07.029

Reference yield: 91.0%

benzo[b]naphtho[2,1-d]thiophene 11,11-dioxide (20841-60-5) + p-toluidine (106-49-0,12221-03-3) → 11-(p-tolyl)-11H-benzo[a]carbazole (1392198-16-1)

Guidance literature:

With potassium hexamethylsilazane; In 1,4-dioxane; toluene; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1002/anie.201503671

Reference yield: 74.0%

→ 11-(p-tolyl)-11H-benzo[a]carbazole (1392198-16-1)

Guidance literature:

With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In 5,5-dimethyl-1,3-cyclohexadiene; for 24h; Reflux; Inert atmosphere;

upstream raw materials:

benzo[b]naphtho[2,1-d]iodol-11-ium trifluoromethanesulfonate

p-toluidine

2-(2-iodophenyl)naphthalene

benzo[b]naphtho[2,1-d]thiophene 11,11-dioxide