trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

Base Information

Chemical Name:trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>
CAS No.:78120-28-2
Molecular Formula:C₂₉H₄₇Cl₄O₁₀PSi₂
Molecular Weight:784.643
Hs Code.:

Synonyms:trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

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Chemical Property of trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

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Technology Process of trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

There total 5 articles about trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 78120-26-0,78120-27-1
allyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

: 78120-28-2
trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

Guidance literature:: hydrogen-activated 1,5-cyclooctadiene-bis-iridium hexafluorophosphate; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1055/s-1981-29429

Reference yield:

: 69304-37-6
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane

: 78120-28-2
trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

Guidance literature:: Multi-step reaction with 4 steps

1: 36 percent / pyridine / 1 h / 0 °C

2: 80 percent / mesitylenesulfonic acid / dimethylformamide / 12 h

3: 63 percent / pyridine / 1 h

4: 95 percent / hydrogen-activated 1,5-cyclooctadiene-bis-iridium hexafluorophosphate / tetrahydrofuran / 2 h / Ambient temperature

With mesitylene sulfonic acid; hydrogen-activated 1,5-cyclooctadiene-bis-iridium hexafluorophosphate; In tetrahydrofuran; pyridine; N,N-dimethyl-formamide;
DOI:10.1055/s-1981-29429

Reference yield:

: 78120-20-4
4,6-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranoside

: 78120-28-2
trans-1-propenyl-3,4-O-(tetraisopropyldisiloxane-1,3-diyl)-α-D-glucopyranosyl 6-O-<2,2,2-trichloroethyl 2-chlorophenyl phosphate>

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / mesitylenesulfonic acid / dimethylformamide / 12 h

2: 63 percent / pyridine / 1 h

3: 95 percent / hydrogen-activated 1,5-cyclooctadiene-bis-iridium hexafluorophosphate / tetrahydrofuran / 2 h / Ambient temperature

With mesitylene sulfonic acid; hydrogen-activated 1,5-cyclooctadiene-bis-iridium hexafluorophosphate; In tetrahydrofuran; pyridine; N,N-dimethyl-formamide;
DOI:10.1055/s-1981-29429