allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

Base Information

Chemical Name:allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside
CAS No.:225924-68-5
Molecular Formula:C₅₃H₆₀O₁₁
Molecular Weight:873.053
Hs Code.:

Synonyms:allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

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Technology Process of allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

There total 20 articles about allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 225924-67-4
allyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-2-O-allyl-3,4-di-O-benzyl-α-D-mannopyranoside

: 225924-68-5
allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

Guidance literature:: With sodium methylate; In methanol;

Reference yield:

: 108869-64-3,130177-78-5,129163-12-8
2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl trichloroacetimidate

: 225924-68-5
allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / molecular sieves (3 Angstroem), TMSOTf / diethyl ether / 0.33 h / Ambient temperature

2: 94 percent / NaOMe / methanol / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; sodium methylate; In methanol; diethyl ether;
DOI:10.1002/(SICI)1099-0690(199905)1999:5<1153::AID-EJOC1153>3.0.CO;2-S

Reference yield:

: 136944-95-1
Allyl-2-O-acetyl-3,4-di-O-benzyl-6-O-tert-butyldiphenylsiloxan-α-D-mannopyranosid

: 225924-68-5
allyl 2-O-allyl-3,4-di-O-benzyl-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / NaOMe / methanol / 6 h / Ambient temperature

2: 90 percent / NaH / dimethylformamide / 2 h / Ambient temperature

3: 92 percent / Bu₄NF / tetrahydrofuran; acetic acid / 96 h / Ambient temperature

4: 86 percent / molecular sieves (3 Angstroem), TMSOTf / diethyl ether / 0.33 h / Ambient temperature

5: 94 percent / NaOMe / methanol / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; tetrabutyl ammonium fluoride; sodium methylate; sodium hydride; In tetrahydrofuran; methanol; diethyl ether; acetic acid; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0690(199905)1999:5<1153::AID-EJOC1153>3.0.CO;2-S