trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

Base Information

Chemical Name:trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane
CAS No.:99598-52-4
Molecular Formula:C₃₁H₃₂O₆S₂
Molecular Weight:564.723
Hs Code.:

Synonyms:trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

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Chemical Property of trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

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Technology Process of trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

There total 10 articles about trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 99598-51-3
4β-<2-(4-methoxybenzocyclobutenyl)-1-p-toluenesulfinyl>-ethyl-5α-methoxymethyl-3-phenylthiomethylenefuran-2-one

: 99598-52-4
cis-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

: 99598-52-4
trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

Guidance literature:: In 1,2-dichloro-benzene; at 180 ℃; for 4h;
DOI:10.1016/S0040-4020(01)96631-1

Reference yield: 61.0%

: 99598-51-3
4β-<2-(4-methoxybenzocyclobutenyl)-1-p-toluenesulfinyl>-ethyl-5α-methoxymethyl-3-phenylthiomethylenefuran-2-one

: 99598-52-4
cis-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

: 99598-52-4
trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

Guidance literature:: In 1,2-dichloro-benzene; at 180 ℃; for 4h;
DOI:10.1016/S0040-4020(01)96631-1

Reference yield:

: 60100-24-5
2-(4-methoxybenzocyclobutenyl)ethyl p-toluenesulfonate

: 99598-52-4
cis-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2-p-toluenesulfinylhydrindane

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / sodium p-toluenesulfinate, sodium iodide / dimethylformamide / 2 h / 80 °C

2: 1.) lithium diisopropylamide; 2.) hexamethylphosphoramide / 1.) tetrahydrofuran, -78 deg C, 1 h; 2.) tetrahydrofuran, -78 deg C, 2 h

3: 1.) 60percent sodium hydride; 2.) 10percent hydrochloric acid / 1.) benzene, r.t., 30 min; 2.) 8 h, r.t., water

4: 1.) methanesulfonyl chloride / 1.) pyridine, r.t., 1 h; 2.) 3 h, r.t.

5: 23 percent / 1,2-dichloro-benzene / 4 h / 180 °C

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; methanesulfonyl chloride; sodium 4-methylbenzenesulfinate; sodium iodide; lithium diisopropyl amide; In N,N-dimethyl-formamide; 1,2-dichloro-benzene;
DOI:10.1016/S0040-4020(01)96631-1