Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside

Base Information

Chemical Name:Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside
CAS No.:383173-64-6
Molecular Formula:C₁₃H₁₇NO₇
Molecular Weight:299.28
Hs Code.:
DSSTox Substance ID:DTXSID00459216
Nikkaji Number:J1.643.647J
Wikidata:Q82282922
Mol file:383173-64-6.mol

Synonyms:383173-64-6;Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside;Benzyl 4-C-nitromethyl-b-D-arabinopyranoside;Benzyl 4-C-Nitromethylene--D-arabinopyranoside;(2R,3S,4S,5R)-5-(nitromethyl)-2-phenylmethoxyoxane-3,4,5-triol;Benzyl 4-C-Nitromethylene-beta-D-arabinopyranoside;Benzyl 4-C-Nitromethylene-?-D-arabinopyranoside;DTXSID00459216;AKOS030242045;Benzyl 4-C-(nitromethyl)-beta-D-arabinopyranoside;Benzyl 4-C-nitrosomethyl beta-D-arabinopyranoside;W-202582;Benzyl 4-C-Nitromethylene- beta -D-arabinopyranoside;(2R,3S,4S,5R)-2-(Benzyloxy)-5-(nitromethyl)tetrahydro-2H-pyran-3,4,5-triol

Suppliers and Price of Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Benzyl4-C-Nitromethylene-β-D-arabinopyranoside
100mg
$ 970.00

TRC
Benzyl4-C-Nitromethylene-β-D-arabinopyranoside
10mg
$ 120.00

Biosynth Carbosynth
Benzyl 4-C-nitromethyl-b-D-arabinopyranoside
25 mg
$ 262.50

Biosynth Carbosynth
Benzyl 4-C-nitromethyl-b-D-arabinopyranoside
10 mg
$ 168.00

Biosynth Carbosynth
Benzyl 4-C-nitromethyl-b-D-arabinopyranoside
5 mg
$ 89.30

American Custom Chemicals Corporation
BENZYL-4-C-NITROMETHYLENE-BETA-D-ARABINOPYRANOSIDE 95.00%
100MG
$ 1593.90

American Custom Chemicals Corporation
BENZYL-4-C-NITROMETHYLENE-BETA-D-ARABINOPYRANOSIDE 95.00%
10MG
$ 704.55

Total 4 raw suppliers

Chemical Property of Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside

Chemical Property:

Melting Point:189-191?C
Storage Temp.:Refrigerator
Solubility.:Acetone
XLogP3:-0.3
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:299.10050188
Heavy Atom Count:21
Complexity:355

Purity/Quality:

98%Min ^*data from raw suppliers

Benzyl4-C-Nitromethylene-β-D-arabinopyranoside ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C(C(C(C(O1)OCC2=CC=CC=C2)O)O)(C[N+](=O)[O-])O
Isomeric SMILES:C1[C@@]([C@H]([C@@H]([C@@H](O1)OCC2=CC=CC=C2)O)O)(C[N+](=O)[O-])O

Technology Process of Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside

There total 2 articles about Benzyl 4-C-Nitromethylene-|A-D-arabinopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 100023-96-9
Benzyl-β-L-threo-pentopyranosid-4-ulose

: 75-52-5
nitromethane

: 383173-69-1
Benzyl 4-C-nitromethyl-α-L-xylo-pyranoside

: 383173-64-6
Benzyl 4-C-nitromethyl-β-D-arabino-pyranoside

Guidance literature:: With triethylamine; at 0 ℃; for 1h;
DOI:10.1002/1521-3765(20010903)7:17<3744::AID-CHEM3744>3.0.CO;2-3

Reference yield:

: 5329-50-0
(-)-benzyl β-D-arabinopyranoside

: 383173-64-6
Benzyl 4-C-nitromethyl-β-D-arabino-pyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: (Bu₃Sn)2O; molecular sieves 3 Angstroem / CHCl₃ / 3.5 h / Heating

1.2: 91 percent / Br₂ / CHCl₃ / 0.05 h / 0 °C

2.1: 43 percent / Et₃N / 1 h / 0 °C

With 3 A molecular sieve; triethylamine; bis(tri-n-butyltin)oxide; In chloroform; 2.1: Henry reaction;
DOI:10.1002/1521-3765(20010903)7:17<3744::AID-CHEM3744>3.0.CO;2-3