Bis(11-hydroxyundecyl) disulfide, 99%

Base Information

• Chemical Name: Bis(11-hydroxyundecyl) disulfide, 99%
• CAS No.: 119438-02-7
• Molecular Formula: C22H46 O2 S2
• Molecular Weight: 406.738
• European Community (EC) Number: 634-252-3
• DSSTox Substance ID: DTXSID00571568
• Nikkaji Number: J815.945I
• Wikidata: Q82459683
• Mol file: 119438-02-7.mol

Synonyms:11,11'-Dihydroxyundecano-1,1'-disulfide;11-Hydroxyundecyl 11'-Hydroxyundecyl 1,1'-Disulfide; Bis(11-hydroxyundecyl)disulfide; Bis(w-hydroxyundecyl)disulfide

Chemical Property of Bis(11-hydroxyundecyl) disulfide, 99%

Chemical Property:

• Melting Point: 80-84 °C
• PSA: 91.06000
• LogP: 7.37420
• Storage Temp.: 2-8°C
• XLogP3: 7.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 23
• Exact Mass: 406.29392305
• Heavy Atom Count: 26
• Complexity: 216

Purity/Quality:

98%,99%, ^*data from raw suppliers

BIS(11-HYDROXYUNDECYL) DISULFIDE 99.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CCCCCO)CCCCCSSCCCCCCCCCCCO

Technology Process of Bis(11-hydroxyundecyl) disulfide, 99%

There total 7 articles about Bis(11-hydroxyundecyl) disulfide, 99% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

11-mercapto-1-undecanol (73768-94-2) → 11-hydroxyundecyldisulfide (119438-02-7)

Guidance literature:

With iodine; In ethanol; for 1h; Ambient temperature;

DOI:10.1080/00397919708004816

Reference yield: 95.0%

thioacetic acid S-(11-hydroxy-undecyl) ester (73768-96-4) → 11-hydroxyundecyldisulfide (119438-02-7)

Guidance literature:

With oxygen; sodium methylate; In methanol; for 12h;

DOI:10.1002/chem.200204544

Reference yield:

thioacetic acid S-(11-hydroxy-undecyl) ester (73768-96-4) → 11-mercapto-1-undecanol (73768-94-2) + 11-hydroxyundecyldisulfide (119438-02-7)

Guidance literature:

With sodium methylate; Yield given;

DOI:10.1080/00397919708004816

upstream raw materials:

11-mercapto-1-undecanol

thioacetic acid S-(11-hydroxy-undecyl) ester

1-Bromo-11-hydroxyundecane

Downstream raw materials:

11,11'-dithiobis[1-(2-bromo-2-methylpropionyloxy)undecane]

C₃₆H₅₂N₂O₈S₂

C₃₆H₅₈O₆S₄

Refernces

• 1、 Belegrinou, Serena,Malinova, Violeta,Masciadri, Raffaello,Meier, Wolfgang. "Efficient two-step synthesis of 11,11′-dithiobis[1-(2-bromo-2- methylpropionyloxy)undecane], a conventional initiator for grafting polymer brushes from gold surfaces via ATRP". . p. 3000 - 3007. Retrieved 2010.
• 2、 Chen, Shengfu,Zheng, Jie,Li, Lingyan,Jiang, Shaoyi. "Strong resistance of phosphorylcholine self-assembled monolayers to protein adsorption: Insights into nonfouling properties of zwitterionic materials". . p. 14473 - 14478. Retrieved 2005.
• 3、 Li, Xue-Mei,Paraschiv, Vasile,Huskens, Jurriaan,Reinhoudt, David N.. "Sulfonic acid-functionalized gold nanoparticles: A colloid-bound catalyst for soft lithographic application on self-assembled monolayers". . p. 4279 - 4284. Retrieved 2003.
• 4、 Jin, Qiao,Xu, Jian-Ping,Ji, Jian,Shen, Jia-Cong. "Zwitterionic phosphorylcholine as a better ligand for stabilizing large biocompatible gold nanoparticles". . p. 3058 - 3060. Retrieved 2008.
• 5、 Caswell,Wilson, James N.,Bunz, Uwe H. F.,Murphy, Catherine J.. "Preferential End-to-End Assembly of Gold Nanorods by Biotin-Streptavidin Connectors". . p. 13914 - 13915. Retrieved 2003.
• 6、 Schoenherr, Holger,Chechik, Victor,Stirling, Charles J. M.,Vancso, G. Julius. "Monitoring surface reactions at an AFM tip: An approach to follow reaction kinetics in self-assembled monolayers on the nanometer scale". . p. 3679 - 3687. Retrieved 2000.
• 7、 Elbert, Katherine C.,Jishkariani, Davit,Wu, Yaoting,Lee, Jennifer D.,Donnio, Bertrand,Murray, Christopher B.. "Design, Self-Assembly, and Switchable Wettability in Hydrophobic, Hydrophilic, and Janus Dendritic Ligand-Gold Nanoparticle Hybrid Materials". . p. 8737 - 8746. Retrieved 2017/10/30.