C₇₇H₁₄₂O₁₂S₂Si₃

Base Information

Chemical Name:C₇₇H₁₄₂O₁₂S₂Si₃
CAS No.:777096-35-2
Molecular Formula:C₇₇H₁₄₂O₁₂S₂Si₃
Molecular Weight:1408.36
Hs Code.:

C<sub>77</sub>H<sub>142</sub>O<sub>12</sub>S<sub>2</sub>Si<sub>3</sub>

Synonyms:C₇₇H₁₄₂O₁₂S₂Si₃

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Chemical Property of C₇₇H₁₄₂O₁₂S₂Si₃

Chemical Property:

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Technology Process of C₇₇H₁₄₂O₁₂S₂Si₃

There total 26 articles about C₇₇H₁₄₂O₁₂S₂Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76513-69-4
(2-trimethylethylsilylethoxy)methyl chloride

: 777096-35-2
C₇₇H₁₄₂O₁₂S₂Si₃

Guidance literature:: Multi-step reaction with 5 steps

1.1: TBAI; DIEA / CH₂Cl₂

2.1: K₂CO₃ / methanol

3.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C

3.2: 75 percent / tetrahydrofuran / 0.17 h

4.1: SO₃*pyr; DMSO

5.1: 80 percent / SmI₂ / tetrahydrofuran / -10 °C

With samarium diiodide; pyridine-SO₃ complex; tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; potassium carbonate; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; 4.1: Parikh-Doering oxidation / 5.1: Evans-Tischenko reduction;
DOI:10.1021/ja0289649

Reference yield:

: 126889-55-2
diethyl(isopropyl)silyl trifluoromethanesulfonate

: 777096-35-2
C₇₇H₁₄₂O₁₂S₂Si₃

Guidance literature:: Multi-step reaction with 18 steps

1.1: 2,6-lutidine

2.1: LiBH₄ / methanol; diethyl ether

3.1: DMAP; Et₃N

4.1: OsO₄; NMO

5.1: aq. NaIO₄

6.1: 97 percent / toluene / 17 h / -78 °C

7.1: K₂CO₃ / methanol

8.1: PPTs / acetone

9.1: 9-BBN / tetrahydrofuran; diethyl ether

9.2: aq. H₂O₂; NaOH / tetrahydrofuran; diethyl ether

10.1: Et₃N

11.1: DDQ / H₂O

12.1: Dess-Martin periodinane

13.1: K₂CO₃ / methanol

14.1: 92 percent / (PhO)3PCH₃I; DIEA / tetrahydrofuran / 0.42 h

15.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C

15.2: 75 percent / tetrahydrofuran / 0.17 h

16.1: SO₃*pyr; DMSO

17.1: 80 percent / SmI₂ / tetrahydrofuran / -10 °C

With 2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; lithium borohydride; 9-borabicyclo[3.3.1]nonane dimer; N-methyl-2-indolinone; samarium diiodide; pyridine-SO₃ complex; methyltriphenoxyphosphonium iodide; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; water; acetone; toluene; 6.1: Roush crotylation / 12.1: Dess-Martin oxidation / 13.1: Wittig olefination / 17.1: Parikh-Doering oxidation / 18.1: Evans-Tischenko reduction;
DOI:10.1021/ja0289649

Reference yield:

: 220213-54-7
(E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol

: 777096-35-2
C₇₇H₁₄₂O₁₂S₂Si₃

Guidance literature:: Multi-step reaction with 20 steps

1.1: DMSO; (COCl)2; NEt₃ / -78 - 20 °C

2.1: Bu₂BOTf; Et₃N

3.1: 2,6-lutidine

4.1: LiBH₄ / methanol; diethyl ether

5.1: DMAP; Et₃N

6.1: OsO₄; NMO

7.1: aq. NaIO₄

8.1: 97 percent / toluene / 17 h / -78 °C

9.1: K₂CO₃ / methanol

10.1: PPTs / acetone

11.1: 9-BBN / tetrahydrofuran; diethyl ether

11.2: aq. H₂O₂; NaOH / tetrahydrofuran; diethyl ether

12.1: Et₃N

13.1: DDQ / H₂O

14.1: Dess-Martin periodinane

15.1: K₂CO₃ / methanol

16.1: 92 percent / (PhO)3PCH₃I; DIEA / tetrahydrofuran / 0.42 h

17.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C

17.2: 75 percent / tetrahydrofuran / 0.17 h

18.1: SO₃*pyr; DMSO

19.1: 80 percent / SmI₂ / tetrahydrofuran / -10 °C

With 2,6-dimethylpyridine; dmap; sodium periodate; osmium(VIII) oxide; lithium borohydride; 9-borabicyclo[3.3.1]nonane dimer; N-methyl-2-indolinone; samarium diiodide; oxalyl dichloride; pyridine-SO₃ complex; di-n-butylboryl trifluoromethanesulfonate; methyltriphenoxyphosphonium iodide; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium carbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; water; acetone; toluene; 1.1: Swern oxidation / 8.1: Roush crotylation / 14.1: Dess-Martin oxidation / 15.1: Wittig olefination / 19.1: Parikh-Doering oxidation / 20.1: Evans-Tischenko reduction;
DOI:10.1021/ja0289649