methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

Base Information

Chemical Name:methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate
CAS No.:1240466-97-0
Molecular Formula:C₄₅H₆₆O₈Si₂
Molecular Weight:791.185
Hs Code.:

methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

Synonyms:methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

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Technology Process of methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

There total 1 articles about methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₇H₂₆O₂Si

: 1240466-85-6
methyl (2S,3R,5S)-5-(tert-butyldimethylsilyloxy)-2-(tert butyldiphenylsilyloxy)-3-methoxy-7-oxoheptanoate

: C₄₅H₆₆O₈Si₂

: 1240466-97-0
methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 1h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.201000369

Reference yield: 99.0%

: 1240466-97-0
methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-7-hydroxy-3-methoxy-10,10-dimethyl-9-oxododec-11-enoate

: 420-37-1
trimethoxonium tetrafluoroborate

: 1240467-00-8
methyl (2S,3R,5R,7R,8R)-8-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)-3,7-dimethoxy-10,10-dimethyl-9-oxododec-11-enoate

Guidance literature:: With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In dichloromethane; at -5 ℃; for 3h; Inert atmosphere; Molecular sieve;
DOI:10.1002/ejoc.201000369