(carbon dioxide)bis(tricyclohexylphosphine)nickel

Base Information

Chemical Name:(carbon dioxide)bis(tricyclohexylphosphine)nickel
CAS No.:57307-01-4
Molecular Formula:C₃₇H₆₆NiO₂P₂
Molecular Weight:663.567
Hs Code.:

Synonyms:(carbon dioxide)bis(tricyclohexylphosphine)nickel

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Chemical Property of (carbon dioxide)bis(tricyclohexylphosphine)nickel

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Technology Process of (carbon dioxide)bis(tricyclohexylphosphine)nickel

There total 3 articles about (carbon dioxide)bis(tricyclohexylphosphine)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.7%

: 39330-67-1
[Ni(cyclododeca-1,5,9-triene)]

: 2622-14-2
tricyclohexylphosphine

: 57307-01-4
(carbon dioxide)bis(tricyclohexylphosphine)nickel

Guidance literature:: With CO₂; In diethyl ether; Ni-compound and PCy3 were dissolved in ether and reacted with continuous stream of CO2 at 0°C for 20 h; ppt. was collected at -50 to -60°C, washed with cold CO2-saturated ether at -50°C and dried under high vac. at -70°C; elem. anal.;

Reference yield:

: [Ni(PCy₃)₂]₂(N₂)

: 57307-01-4
(carbon dioxide)bis(tricyclohexylphosphine)nickel

Guidance literature:: With carbon dioxide; Ni complex placed into pressure reaction vesel under N2, cooled to -100°C, liquid CO2 condensed to vessel, system sealed, warmed to roomtemp., stirred;
DOI:10.1021/ja00383a026