Mn(CO)5Si(p-Tol)2H

Base Information

Chemical Name:Mn(CO)5Si(p-Tol)2H
CAS No.:458567-48-1
Molecular Formula:C₁₉H₁₅MnO₅Si
Molecular Weight:406.349
Hs Code.:

Synonyms:Mn(CO)5Si(p-Tol)2H

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Chemical Property of Mn(CO)5Si(p-Tol)2H

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Technology Process of Mn(CO)5Si(p-Tol)2H

There total 1 articles about Mn(CO)5Si(p-Tol)2H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 10170-69-1
dimanganese decacarbonyl

: 18551-61-6
chlorobis(4-methylphenyl)silane

: 458567-48-1
Mn(CO)5Si(p-Tol)2H

Guidance literature:: With sodium amalgam; In tetrahydrofuran; hexane; THF soln. of NaMn(CO)5 prepd. from Mn2(CO)10 and Na/Hg under N2, solventwas removed under vac., soln. of p-Tol2SiHCl in hexane added at -43.deg ree.C by syringe under Ar, mixt. was stirred at room temp. for 12 h under N2; filtered through Celite under N2, evapd., residue was recrystd. from pentane; elem. anal.;
DOI:10.1016/S0022-328X(02)01188-9

Reference yield: 52.0%

: 458567-48-1
Mn(CO)5Si(p-Tol)2H

: 10170-69-1
dimanganese decacarbonyl

Guidance literature:: With sodium cyanoborohydride; In tetrahydrofuran; byproducts: bis(p-tolyl)silane; under N2; a THF soln. of Mn-complex was added to a suspn. of NaBH3CN in THF at -43°C, mixt. was stirred for 1d at room temp.; evapd. in vacuo, residue was extd. with hexane, filtered through a Celite pad, evapd., flash chromy. (SiO2, toluene/hexane (1/5));
DOI:10.1016/S0022-328X(02)01188-9

Reference yield:

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 458567-48-1
Mn(CO)5Si(p-Tol)2H

: [H(p-Til)2Si*THF]⁽¹⁺⁾[Mn(CO)5]^(1-)

Guidance literature:: In tetrahydrofuran; Mn- complex was dissolved in THF under N2; not isolated; detected by IR spectral data;
DOI:10.1016/S0022-328X(02)01188-9