cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate

Base Information

• Chemical Name: cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate
• CAS No.: 129032-18-4
• Molecular Formula: C₂₁H₃₀O₆
• Molecular Weight: 378.466
• Mol file: 129032-18-4.mol

Synonyms:cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate

Chemical Property of cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate

There total 1 articles about cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethyl cyclohexane-1,3,5-tricarboxylate (52831-11-5) + allyl bromide (106-95-6) → cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate (129032-18-4)

Guidance literature:

With lithium diisopropyl amide; Yield given. Multistep reaction; 1.) toluene, 0 deg C, 15 min, 2.) from 0 deg C to 75 deg C, 1.5 h;

Reference yield:

cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate (129032-18-4) → trimethyl-cis,cis-1,3,5-tripropyl-1,3,5-cyclohexane-tricarboxylate (131589-70-3)

Guidance literature:

With hydrogen; palladium;

DOI:10.1021/ja00172a049

Reference yield:

cis,cis-trimethyl 1,3,5-triallylcyclohexane-1,3,5-tricarboxylate (129032-18-4) → cis,cis-1,3,5-tripropylcyclohexyl 1,3,5-tricarboxylic acid (129063-52-1)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂ / 10percent Pd/C / ethyl acetate / 3 h / 2585.7 Torr / Ambient temperature

2: 97 percent / aq. potassium hydroxide / ethanol / 12 h / Heating

With potassium hydroxide; hydrogen; palladium on activated charcoal; In ethanol; ethyl acetate;

upstream raw materials:

trimethyl cyclohexane-1,3,5-tricarboxylate

allyl bromide

Downstream raw materials:

trimethyl-cis,cis-1,3,5-tripropyl-1,3,5-cyclohexane-tricarboxylate

cis,cis-1,3,5-triallylcyclohexane-1,3,5-tricarboxylic acid

cis,cis-1,3,5-tripropylcyclohexyl 1,3,5-tricarboxylic acid