3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

Base Information

Chemical Name:3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol
CAS No.:159425-51-1
Molecular Formula:C₂₉H₃₂O₉
Molecular Weight:524.568
Hs Code.:

Synonyms:3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

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Chemical Property of 3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

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Technology Process of 3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

There total 11 articles about 3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 159425-50-0
2-(1,3-dioxanyl)-6'-(benzyloxy)-2,6-bis(methoxymethoxy)-4-<<(tert-butyldimethylsilyl)oxy>methyl>benzophenone

: 159425-51-1
3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 1.5h; Ambient temperature;
DOI:10.1021/jo00101a032

Reference yield:

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 159425-51-1
3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

Guidance literature:: Multi-step reaction with 6 steps

1: 75 percent / diisopropylethylamine / CH₂Cl₂ / Ambient temperature

2: 100 percent / LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

3: 87 percent / imidazole / CH₂Cl₂

4: 73 percent / n-BuLi / tetrahydrofuran; hexane / 1.) 0 deg C, 60 min, 2.) 0 deg C, 2 h; r.t., overnight

5: 93 percent / MnO₂ / CH₂Cl₂ / 48 h / Ambient temperature

6: 88 percent / TBAF / tetrahydrofuran / 1.5 h / Ambient temperature

With 1H-imidazole; manganese(IV) oxide; lithium aluminium tetrahydride; n-butyllithium; tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo00101a032

Reference yield:

: 1700-30-7
(3-(benzyloxy)phenyl)methanol

: 159425-51-1
3,5-bis(methoxymethoxy)-4-<(2-benzyloxy)-6-(1,3-dioxanyl)benzoyl>benzyl alcohol

Guidance literature:: Multi-step reaction with 7 steps

1: 55 percent / n-BuLi, BrF₂CH₂CH₂F₂Br / toluene / -20 °C

2: 90 percent / NaBr, NaOCl, TEMPO / tetrahydrofuran / 3 h / 0 °C

3: 96 percent / p-TSA*H₂O / toluene / 1.5 h / Heating

4: 79 percent / n-BuLi / tetrahydrofuran; hexane / 1.) -60 deg C, 15 min, 2.) -65 deg C, 4 h; r.t., 16 h

5: 73 percent / n-BuLi / tetrahydrofuran; hexane / 1.) 0 deg C, 60 min, 2.) 0 deg C, 2 h; r.t., overnight

6: 93 percent / MnO₂ / CH₂Cl₂ / 48 h / Ambient temperature

7: 88 percent / TBAF / tetrahydrofuran / 1.5 h / Ambient temperature

With manganese(IV) oxide; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; n-butyllithium; BrF₂CH₂CH₂F₂Br; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; sodium bromide; In tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1021/jo00101a032