4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine

Base Information

• Chemical Name: 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine
• CAS No.: 1379584-02-7
• Molecular Formula: C₃₅H₂₄N₄O₂
• Molecular Weight: 532.601
• Mol file: 1379584-02-7.mol

Synonyms:4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine

Chemical Property of 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine

There total 2 articles about 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.3%

4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine (1379584-01-6) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine (1379584-02-7)

Guidance literature:

With trichlorophosphate; for 12.1667h; Cooling with ice; Reflux;

DOI:10.1016/j.dyepig.2012.03.020

Reference yield:

4′-(4-(N,N-diphenylamino)-phenyl)-2,2′:6′,2″-terpyridine (408359-98-8) → 4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine (1379584-02-7)

Guidance literature:

Multi-step reaction with 2 steps

1: trichlorophosphate / 12.17 h / Cooling with ice; Reflux

2: trichlorophosphate / 12.17 h / Cooling with ice; Reflux

With trichlorophosphate;

DOI:10.1016/j.dyepig.2012.03.020

Reference yield: 70.8%

4''',4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine (1379584-02-7) → 4''',4''-(4'-(4-(diphenylamino)phenyl)dibenzoic acid)-2,2':6',2''-terpyridine (1379584-03-8)

Guidance literature:

With potassium permanganate; potassium carbonate; In water; acetone; for 12h; Reflux;

DOI:10.1016/j.dyepig.2012.03.020

upstream raw materials:

4''-(4'-(4-(diphenylamino)phenyl)aldehyde)-2,2':6',2''-terpyridine

N,N-dimethyl-formamide

4′-(4-(N,N-diphenylamino)-phenyl)-2,2′:6′,2″-terpyridine

Downstream raw materials:

4''',4''-(4'-(4-(diphenylamino)phenyl)dibenzoic acid)-2,2':6',2''-terpyridine

4'-(4-2-[dimethyl-4,4'-(phenylazanediyl)dibenzoate]phenyl)-2,2':6',2''-terpyridine