(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

Base Information

Chemical Name:(phenylethynyl)(1-naphthyl)(p-tolyl)stibane
CAS No.:312308-61-5
Molecular Formula:C₂₅H₁₉Sb
Molecular Weight:441.176
Hs Code.:

Synonyms:(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (phenylethynyl)(1-naphthyl)(p-tolyl)stibane

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Technology Process of (phenylethynyl)(1-naphthyl)(p-tolyl)stibane

There total 1 articles about (phenylethynyl)(1-naphthyl)(p-tolyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 90-11-9
1-Bromonaphthalene

: 114447-66-4
bis(phenylethynyl)(p-tolyl)stibane

: 312308-61-5
(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

Guidance literature:: With Mg; In diethyl ether; (Ar); Sb compd. soln. added to 1-naphthylmagnesium bromide soln. (prepd.of 1-bromonaphthalene and Mg) over 30 min at 0°C, stirred for 16 h at room temp.; cooled, dild. (C6H6 and H2O), the aq. layer extd. (C6H6), the combined org. layer washed (brine), dried (Na2SO4), evapd. (vac.), chromy. (SiO2, hexane/C6H6); elem. anal.;
DOI:10.1016/S0022-328X(02)01622-4

Reference yield: 90.0%

: 312308-61-5
(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

: 52711-30-5
1-bromo-2-(methoxymethyl)benzene

: 891191-65-4,891191-58-5,891191-64-3
(+/-)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Guidance literature:: With n-BuLi; In diethyl ether; hexane; byproducts: LiCCPh; (Ar); soln. of BuLi in hexane and BrC6H4CH2OMe were reacted in ether at low temp.; Sb compd. was added with stirring over 50 min at -20°C; stirred at -20°C for 2 h; kept at room temp. for 1 h; dild. with ether and H2O; org. layer septd.; aq. layer extd. (ether); combined org. phase washed (brine); dried (MgSO4); evapd. (vac.); chromd. (silica gel, hexane/CH2Cl2, 4/1); recrystd. (hexane/C6H6); elem. anal.;
DOI:10.1016/j.jorganchem.2005.10.042

Reference yield: 88.0%

: 312308-61-5
(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

: 62336-24-7
(2-bromophenyl)diphenylphosphane

: 891191-59-6
(+/-)-(2-diphenylphosphinophenyl)(1-naphthyl)(4-tolyl)stibane

Guidance literature:: With n-BuLi; In diethyl ether; hexane; byproducts: LiCCPh; (Ar); soln. of BuLi in hexane and BrC6H4PPh2 were reacted in ether at low temp.; Sb compd. was added with stirring over 25 min at -80°C; stirred for 30 min; slowly warmed to -20°C; dild. with C6H6 and H2O; org. layer septd.; aq. layer extd. (C6H6); combined org. phase washed (brine); dried (MgSO4); evapd. (vac.); chromd. (silica gel, hexane/C6H6, 5/1);
DOI:10.1016/j.jorganchem.2005.10.042