C₆₈H₈₇Si₂NO₁₀

Base Information

• Chemical Name: C₆₈H₈₇Si₂NO₁₀
• CAS No.: 930807-92-4
• Molecular Formula: C₆₈H₈₇NO₁₀Si₂
• Molecular Weight: 1134.61
• Mol file: 930807-92-4.mol

Synonyms:C₆₈H₈₇Si₂NO₁₀

Chemical Property of C₆₈H₈₇Si₂NO₁₀

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₈H₈₇Si₂NO₁₀

There total 4 articles about C₆₈H₈₇Si₂NO₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

C68H89Si2NO10 (930807-91-3) → C68H87Si2NO10 (930807-92-4)

Guidance literature:

With 2,6-dimethylpyridine; Dess-Martin periodane; In dichloromethane; for 0.5h;

DOI:10.1002/anie.200603656

Reference yield:

C70H91Si2NO11 (930807-90-2) → C68H87Si2NO10 (930807-92-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / diisobutylaluminium hydride / CH₂Cl₂; toluene / 1 h / -78 °C

2: 92 percent / Dess-Martin periodinane; 2,6-lutidine / CH₂Cl₂ / 0.5 h

With 2,6-dimethylpyridine; diisobutylaluminium hydride; Dess-Martin periodane; In dichloromethane; toluene; 2: Dess-Martin oxidation;

DOI:10.1002/anie.200603656

Reference yield:

C65H85Si2O10N (930807-88-8) → C68H87Si2NO10 (930807-92-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 92 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

2: 94 percent / toluene / 24 h / 80 °C

3: 95 percent / diisobutylaluminium hydride / CH₂Cl₂; toluene / 1 h / -78 °C

4: 92 percent / Dess-Martin periodinane; 2,6-lutidine / CH₂Cl₂ / 0.5 h

With 2,6-dimethylpyridine; diisobutylaluminium hydride; Dess-Martin periodane; In dichloromethane; toluene; 1: Dess-Martin oxidation / 4: Dess-Martin oxidation;

DOI:10.1002/anie.200603656

upstream raw materials:

C₆₈H₈₉Si₂NO₁₀

C₆₅H₈₅Si₂O₁₀N

C₆₅H₈₃Si₂O₁₀N

C₇₀H₉₁Si₂NO₁₁

Downstream raw materials:

C₇₄H₉₆Si₂NO₁₀Br

2-((2R,3S,4S,5R,6R)-6-((E)-1-(2-(((2S,4R,6R)-6-((1R,2E,4E,6R,8E)-9-bromo-1-(tert-butyldiphenylsilanyloxy)-6-methoxy-3-methylnona-2,4,8-trienyl)-2,4-dimethoxytetrahydro-2H-pyran-2-yl)methyl)oxazol-4-yl)prop-1-en-2-yl)-4-(4-methoxybenzyloxy)-3,5-dimethyltetrahydro-2H-pyran-2-yl)acetaldehyde

2-((2R,3S,4S,5R,6R)-6-((E)-1-(2-(((2S,4R,6R)-6-((1R,2E,4E,6R,8E)-9-bromo-1-(tert-butyldiphenylsilanyloxy)-6-methoxy-3-methylnona-2,4,8-trienyl)-2,4-dimethoxytetrahydro-2H-pyran-2-yl)methyl)oxazol-4-yl)prop-1-en-2-yl)-4-(4-methoxybenzyloxy)-3,5-dimethyltetrahydro-2H-pyran-2-yl)ethanol

C₆₂H₈₂SiNBrO₁₁