methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Base Information

Chemical Name:methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside
CAS No.:864815-49-6
Molecular Formula:C₄₂H₄₀ClNO₁₁
Molecular Weight:770.233
Hs Code.:

Synonyms:methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

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Chemical Property of methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

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Technology Process of methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

There total 4 articles about methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 864815-46-3
ethyl 3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-1-thio-α-L-rhamnopyranoside

: 81927-56-2
methyl 4,6-O-benzylidene-2-deoxy-2-phthalimide-β-D-glucopyranoside

: 864815-49-6
methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: ethyl 3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-1-thio-α-L-rhamnopyranoside; methyl 4,6-O-benzylidene-2-deoxy-2-phthalimide-β-D-glucopyranoside; With 3 A molecular sieve; In dichloromethane; for 1h;

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; for 0.25h;
DOI:10.1039/b416106h

Reference yield:

: Benzoic acid (2S,3S,4R)-3-benzyloxy-5,6-dichloro-2-methyl-tetrahydro-pyran-4-yl ester

: 864815-49-6
methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: 1.99 g / AgOAc / 12 h / 20 °C

2.1: 91 percent / 3 Angstroem molecular sieves; BF₃*OEt₂ / CH₂Cl₂ / 2 h

3.1: 3 Angstroem molecular sieves / CH₂Cl₂ / 1 h

3.2: 92 percent / NIS; AgOTf / CH₂Cl₂ / 0.25 h

With 3 A molecular sieve; boron trifluoride diethyl etherate; silver(I) acetate; In dichloromethane; 1.1: Koenig-Knorr glycosylation;
DOI:10.1039/b416106h

Reference yield:

: Benzoic acid (4R,5S,6S)-2-acetoxy-5-benzyloxy-3-chloro-6-methyl-tetrahydro-pyran-4-yl ester

: 864815-49-6
methyl (3-O-benzoyl-4-O-benzyl-2-chloro-2-deoxy-α-L-rhamnopyranosyl)-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 91 percent / 3 Angstroem molecular sieves; BF₃*OEt₂ / CH₂Cl₂ / 2 h

2.1: 3 Angstroem molecular sieves / CH₂Cl₂ / 1 h

2.2: 92 percent / NIS; AgOTf / CH₂Cl₂ / 0.25 h

With 3 A molecular sieve; boron trifluoride diethyl etherate; In dichloromethane;
DOI:10.1039/b416106h