1,6-bis[Au(PPh₃)]-3-bromopyrene

Base Information

• Chemical Name: 1,6-bis[Au(PPh₃)]-3-bromopyrene
• CAS No.: 1004759-98-1
• Molecular Formula: C₅₂H₃₇Au₂BrP₂
• Molecular Weight: 1197.65
• Mol file: 1004759-98-1.mol

Synonyms:1,6-bis[Au(PPh₃)]-3-bromopyrene

Chemical Property of 1,6-bis[Au(PPh₃)]-3-bromopyrene

Chemical Property:

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Technology Process of 1,6-bis[Au(PPh₃)]-3-bromopyrene

There total 1 articles about 1,6-bis[Au(PPh₃)]-3-bromopyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 1,3,6-tribromopyrene (38303-36-5) → 1,6-bis[Au(PPh3)]-3-bromopyrene (1004759-98-1)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; (N2); using Schlenk techniques; addn. of n-butyllithium (3 equiv.) in hexane to stirred soln. of 1,3,6-tribromopyrene (1 equiv.) in Et2O at 0°C for 10 min; addn. of Au(PPh3)Cl (3 equiv.); warming to room temp.; stirring for 2 h; addn. of CH2Cl2; filtration, concn., addn. of hexane; pptn., recrystn. by layering of Et2O onto CH2Cl2 soln.; elem. anal.;

DOI:10.1021/om700716p

upstream raw materials:

(triphenylphosphine)gold(I) chloride

1,3,6-tribromopyrene

Refernces