IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

Base Information

Chemical Name:IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2
CAS No.:91685-25-5
Molecular Formula:2BF₄*C₅₃H₄₈ClIrOP₄
Molecular Weight:1226.14
Hs Code.:

IrCl(CO)(((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>)2)2<sup>(2+)</sup>*2BF<sub>4</sub><sup>(1-)</sup> = [IrCl(CO)(((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>)2)2](BF<sub>4</sub>)2

Synonyms:IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

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Chemical Property of IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

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Technology Process of IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

There total 2 articles about IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 13826-83-0
ammonium tetrafluroborate

: 15390-38-2,15131-25-6
bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride

: 91685-25-5
IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

Guidance literature:: With CO; NOCl; In dichloromethane; Ir complex soln. satd. with CO, NOCl gas bubbled, pptd. with THF, filtered, washed with THF, dried in vac., treated with NH4BF4 (metathesis); recrystd. (CH2Cl2/Et2O); elem. anal.;

Reference yield:

: 1282-37-7
ferrocenium(III) tetrafluoroborate

: 15390-38-2,15131-25-6
bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride

: 91685-25-5
IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

Guidance literature:: With CO; In dichloromethane; Ir complex soln. satd. with CO added to Fe complex in CH2Cl2, purged with CO, stirred overnight; pptd. (THF), filtered, recrystd. (CH2Cl2/THF);

Reference yield:

: lithium triethyl borodeuteride

: 91685-25-5
IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2

: 94570-15-7
IrCl(C⁽²⁾HO)(((C₆H₅)2PCH₂)2)2⁽¹⁺⁾*BF₄^(1-) = [IrCl(C⁽²⁾HO)(((C₆H₅)2PCH₂)2)2](BF₄)

Guidance literature:: In dichloromethane; (N2), CH2Cl2 added to the Ir-complex, cooled to -78°C, Li-compd.added, stirred at -78°C for 0.5 h, allowed to warm slowly to room temp.; ether added, pptd., recrystd. at -78°C;
DOI:10.1021/om00122a029