(2R,5S,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

Base Information

Chemical Name:(2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran
CAS No.:98128-10-0
Molecular Formula:C₂₀H₂₄O₃
Molecular Weight:312.409
Hs Code.:

Synonyms:(2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

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Chemical Property of (2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

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Technology Process of (2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

There total 4 articles about (2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 98128-09-7
(2R*,3S*,4R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-4-hydroxy-2,3-dihydro-4H-pyran

: 100-51-6,185532-71-2
benzyl alcohol

: 98128-10-0
(2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 1.5h;
DOI:10.1021/ja00309a037

Reference yield:

: 52480-43-0
4,5-dimethyl-2-formylfuran

: 98128-10-0
(2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: 2.) trifluoroacetic acid / 1.) Yb(fod)3 / 1.) CDCl₃, 24 h, RT; 2.) CDCl₃, CH₂Cl₂, 5 min

2: 89 percent / LAH / diethyl ether / 0.25 h

3: 91 percent / p-toluenesulfonic acid / benzene / 1.5 h

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; trifluoroacetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; In diethyl ether; benzene;
DOI:10.1021/ja00309a037

Reference yield:

: 72486-93-2
1-methoxy-2-methyl-3-trimethylsiloxy-1,3-pentadiene

: 98128-10-0
(2R*,5S*,6R*)-6-(4,5-dimethyl-2-furyl)-3,5-dimethyl-2-(benzyloxy)-5,6-dihydro-2H-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: 2.) trifluoroacetic acid / 1.) Yb(fod)3 / 1.) CDCl₃, 24 h, RT; 2.) CDCl₃, CH₂Cl₂, 5 min

2: 89 percent / LAH / diethyl ether / 0.25 h

3: 91 percent / p-toluenesulfonic acid / benzene / 1.5 h

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; trifluoroacetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; In diethyl ether; benzene;
DOI:10.1021/ja00309a037