C₃₂H₄₈O₆Si

Base Information

Chemical Name:C₃₂H₄₈O₆Si
CAS No.:1263144-07-5
Molecular Formula:C₃₂H₄₈O₆Si
Molecular Weight:556.815
Hs Code.:

C<sub>32</sub>H<sub>48</sub>O<sub>6</sub>Si

Synonyms:C₃₂H₄₈O₆Si

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Chemical Property of C₃₂H₄₈O₆Si

Chemical Property:

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Technology Process of C₃₂H₄₈O₆Si

There total 18 articles about C₃₂H₄₈O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1263144-09-7
C₁₄H₁₆N₄O₄S

: 1263144-08-6
C₂₅H₃₈O₅Si

: C₃₂H₄₈O₆Si

: 1263144-07-5
C₃₂H₄₈O₆Si

Guidance literature:: C₁₄H₁₆N₄O₄S; With potassium hexamethylsilazane; In 1,2-dimethoxyethane; at -75 - -65 ℃; for 0.5h;

C₂₅H₃₈O₅Si; In 1,2-dimethoxyethane; at -75 - 0 ℃; for 3h; optical yield given as %de;
DOI:10.1016/j.tet.2010.11.017

Reference yield:

: 1195988-14-7
C₂₃H₃₆O₄Si

: C₃₂H₄₈O₆Si

: 1263144-07-5
C₃₂H₄₈O₆Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.5 h / -78 - -50 °C

1.2: -78 - 20 °C

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 13 h / 0 - 20 °C

3.1: titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; Cumene hydroperoxide / dichloromethane / 9 h / -40 - -25 °C / Molecular sieve

3.2: 1.5 h / -25 - 20 °C

4.1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 13.83 h / 20 °C

5.1: potassium carbonate / methanol / 4 h / 20 °C

6.1: copper(l) iodide / tetrahydrofuran / 1.5 h / -40 °C

7.1: dmap; triethylamine / 2.5 h / 20 °C

8.1: osmium(VIII) oxide; AD-mix-β; 1,4-bis(9-O-dihydroquinidine)phthalazine / water; tert-butyl alcohol / 70 h / 0 - 20 °C

9.1: silica-supported sodium periodate / dichloromethane / 0.67 h / 0 - 20 °C

10.1: tetrahydrofuran / 13.83 h / -40 °C

11.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.33 h / -78 °C

11.2: -78 - 20 °C

12.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / dichloromethane / 44 h / -40 - -15 °C / Molecular sieve

12.2: 3 h / -15 - 20 °C

13.1: silver nitrate; triethylamine / tetrahydrofuran / 0.75 h / 0 °C

13.2: 15 h / 0 - 20 °C

14.1: camphor-10-sulfonic acid / methanol; dichloromethane / 2.5 h / 0 - 20 °C

15.1: dimethyl sulfoxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / 3 h / 20 °C

16.1: potassium hexamethylsilazane / 1,2-dimethoxyethane / 0.5 h / -75 - -65 °C

16.2: 3 h / -75 - 0 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; copper(l) iodide; osmium(VIII) oxide; diethyl (2S,3S)-tartrate; diethyl (2R,3R)-tartrate; silica-supported sodium periodate; Cumene hydroperoxide; AD-mix-β; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; potassium hexamethylsilazane; diisobutylaluminium hydride; di(n-butyl)tin oxide; potassium carbonate; silver nitrate; dimethyl sulfoxide; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; water; tert-butyl alcohol; 3.1: Sharpless epoxidation / 10.1: Wittig reaction / 12.1: Sharpless epoxidation / 16.1: Julia-Kocienski reaction / 16.2: Julia-Kocienski reaction;
DOI:10.1016/j.tet.2010.11.017

Reference yield:

: 1195988-26-1
C₂₁H₃₄O₃Si

: C₃₂H₄₈O₆Si

: 1263144-07-5
C₃₂H₄₈O₆Si

Guidance literature:: Multi-step reaction with 15 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 13 h / 0 - 20 °C

2.1: titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; Cumene hydroperoxide / dichloromethane / 9 h / -40 - -25 °C / Molecular sieve

2.2: 1.5 h / -25 - 20 °C

3.1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 13.83 h / 20 °C

4.1: potassium carbonate / methanol / 4 h / 20 °C

5.1: copper(l) iodide / tetrahydrofuran / 1.5 h / -40 °C

6.1: dmap; triethylamine / 2.5 h / 20 °C

7.1: osmium(VIII) oxide; AD-mix-β; 1,4-bis(9-O-dihydroquinidine)phthalazine / water; tert-butyl alcohol / 70 h / 0 - 20 °C

8.1: silica-supported sodium periodate / dichloromethane / 0.67 h / 0 - 20 °C

9.1: tetrahydrofuran / 13.83 h / -40 °C

10.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.33 h / -78 °C

10.2: -78 - 20 °C

11.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / dichloromethane / 44 h / -40 - -15 °C / Molecular sieve

11.2: 3 h / -15 - 20 °C

12.1: silver nitrate; triethylamine / tetrahydrofuran / 0.75 h / 0 °C

12.2: 15 h / 0 - 20 °C

13.1: camphor-10-sulfonic acid / methanol; dichloromethane / 2.5 h / 0 - 20 °C

14.1: dimethyl sulfoxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / 3 h / 20 °C

15.1: potassium hexamethylsilazane / 1,2-dimethoxyethane / 0.5 h / -75 - -65 °C

15.2: 3 h / -75 - 0 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; copper(l) iodide; osmium(VIII) oxide; diethyl (2S,3S)-tartrate; diethyl (2R,3R)-tartrate; silica-supported sodium periodate; Cumene hydroperoxide; AD-mix-β; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; potassium hexamethylsilazane; diisobutylaluminium hydride; di(n-butyl)tin oxide; potassium carbonate; silver nitrate; dimethyl sulfoxide; 1,4-bis(9-O-dihydroquinidine)phthalazine; triethylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; water; tert-butyl alcohol; 2.1: Sharpless epoxidation / 9.1: Wittig reaction / 11.1: Sharpless epoxidation / 15.1: Julia-Kocienski reaction / 15.2: Julia-Kocienski reaction;
DOI:10.1016/j.tet.2010.11.017