N,N-Bis-Boc-N-allylamine

Base Information

• Chemical Name: N,N-Bis-Boc-N-allylamine
• CAS No.: 115269-99-3
• Molecular Formula: C13H23NO4
• Molecular Weight: 257.33
• European Community (EC) Number: 675-927-2
• DSSTox Substance ID: DTXSID80437274
• Nikkaji Number: J851.540I
• Wikidata: Q72444377
• Mol file: 115269-99-3.mol

Synonyms:N,N-Bis-Boc-N-allylamine;115269-99-3;N,N-DIBOC-ALLYLAMINE;tert-butyl N-[(2-methylpropan-2-yl)oxycarbonyl]-N-prop-2-enylcarbamate;N,N-Di-Boc-allylamine;SCHEMBL2622073;DTXSID80437274;Allylbis(tert-butoxycarbonyl)amine;YLJIUBLSFUQBSL-UHFFFAOYSA-N;di-tert-butyl allyliminodicarbonate;MFCD04115302;Di (tert-butyl) allylimidodicarbonate;AKOS015841382;N,2-Bis(tert-butoxycarbonyl)allylamine;SB66479;AS-37071;CS-0170869;FT-0602709;1,3-BIs(1,1-dimethylethyl) 2-(2-propen-1-yl)imidodicarbonate;Imidodicarbonic acid, 2-(2-propen-1-yl)-, 1,3-bis(1,1-dimethylethyl) ester

Chemical Property of N,N-Bis-Boc-N-allylamine

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.46
• Boiling Point: 293.597 °C at 760 mmHg
• Flash Point: 131.363 °C
• PSA: 55.84000
• Density: 1.019g/cm³
• LogP: 3.34460
• Storage Temp.: 2-8°C
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 257.16270821
• Heavy Atom Count: 18
• Complexity: 295

Purity/Quality:

97% ^*data from raw suppliers

N,N-Bis-Boc-N-allylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)OC(=O)N(CC=C)C(=O)OC(C)(C)C

Technology Process of N,N-Bis-Boc-N-allylamine

There total 10 articles about N,N-Bis-Boc-N-allylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

potassium bis(tert-butoxycarbonyl)amide (89004-82-0) + allyl bromide (106-95-6) → N,N-bis(tert-butoxycarbonyl)allylamine (115269-99-3)

Guidance literature:

In N,N-dimethyl-formamide; at 100 ℃; for 2h;

DOI:10.1016/S0968-0896(99)00091-7

Reference yield: 95.0%

iminodicarboxylic acid di-tert-butyl ester (51779-32-9) + allyl bromide (106-95-6) → N,N-bis(tert-butoxycarbonyl)allylamine (115269-99-3)

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; In 2-methyltetrahydrofuran; water; at 20 - 50 ℃; for 1h;

Reference yield: 95.0%

di-tert-butyl dicarbonate (24424-99-5) + allyl bromide (106-95-6) → N,N-bis(tert-butoxycarbonyl)allylamine (115269-99-3)

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; In various solvent(s); at 35 ℃; for 2h;

upstream raw materials:

Allyl acetate

iminodicarboxylic acid di-tert-butyl ester

allyl bromide

di-tert-butyl dicarbonate

Downstream raw materials:

3--1-phenyl-1-propene

(E)-N,N-bis(tert-butoxycarbonyl)-3-(2,3,4,5,6-pentafluorophenyl)prop-2-en-1-amine