triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin

Base Information

• Chemical Name: triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin
• CAS No.: 124219-35-8
• Molecular Formula: C₁₃H₁₈F₄OSn
• Molecular Weight: 384.989
• Mol file: 124219-35-8.mol

Synonyms:triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin

Chemical Property of triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin

There total 2 articles about triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorotriethylstannane (994-31-0) → triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin (124219-35-8)

Guidance literature:

Multi-step reaction with 3 steps

1: butyllithium / hexane; diethyl ether

2: dichloromethane

3: butyllithium / hexane; diethyl ether

With butyllithium; In diethyl ether; hexane; dichloromethane;

DOI:10.1016/0022-328X(89)85436-1

Reference yield:

triethylpentafluoroyphenyltin (27245-11-0) → triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin (124219-35-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: butyllithium / hexane; diethyl ether

With butyllithium; In diethyl ether; hexane; dichloromethane;

DOI:10.1016/0022-328X(89)85436-1

Reference yield: 24.0%

(dicyclopentadiene)platinum(II) dichloride (12083-92-0) + triethyl(2,3,5,6-tetrafluoro-4-methoxyphenyl)tin (124219-35-8) → chloro(η4-dicyclopentadiene)(2,3,5,6-tetrafluoro-4-methoxyphenyl)platinum(II) + (η4-dicyclopentadiene)bis(2,3,5,6-tetrafluoro-4-methoxyphenyl)platinum(II) + chlorotriethylstannane (994-31-0)

Guidance literature:

In dichloromethane; under nitrogen, 41°C, 48 h, some decompn. obsd.; TLC monitoring, solvent removed (vac.); residue washed (warm petroleum ether; purifn. chromy. (silica, CH2Cl2/petroleum ether 2/1, v/v), crystn. from eluant solvent; mixt. of two isomers (by (19)F-NMR);

DOI:10.1016/0022-328X(89)85436-1

upstream raw materials:

triethylpentafluoroyphenyltin

chlorotriethylstannane

Downstream raw materials:

chlorotriethylstannane

triethylpentafluoroyphenyltin