2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Base Information

Chemical Name:2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane
CAS No.:186091-02-1
Molecular Formula:C₄₁H₄₀N₂O₁₁S
Molecular Weight:768.841
Hs Code.:

Synonyms:2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Suppliers and Price of 2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

There total 10 articles about 2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 75-18-3
dimethylsulfide

: 186091-01-0
2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-5-pentanol

: 186091-02-1
2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Guidance literature:: With dibenzoyl peroxide; In acetonitrile; at 0 ℃; for 3h;
DOI:10.1016/S0008-6215(96)00207-8

Reference yield:

: 6318-30-5
2,2-dimethyl-4-(3-hydroxypropyl)-1,3-dioxolane

: 186091-02-1
2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Guidance literature:: Multi-step reaction with 9 steps

1: 95 percent / NaH, Bu₄NI / dimethylformamide / 3 h / Ambient temperature

2: 94 percent / aq. acetic acid / Ambient temperature

3: 88 percent / 4-dimethylaminopyridine / pyridine / 48 h / Ambient temperature

4: 84 percent / PCC / pyridine; CH₂Cl₂ / 96 h

5: 77 percent / aq. acetic acid / 2 h / Ambient temperature

6: 1.) hydroxylamine-O-sulfonic acid, NH₃, 2.) Et₃N, I₂ / 1.) MeOH, -20 deg C, 2 h, 2.) MeOH, 0 deg C, 20 min

7: 1.) tetramethylurea, silver trifluoromethanesulfonate, 4A molecular sieves / 1.) CH₂Cl₂, rt, 1 h, 2.) CH₂Cl₂, -20 deg C, 4 h

8: 81 percent / N-bromosucinimide, CaCO₃, Br₂ / CCl₄; H₂O / 3 h / Ambient temperature

9: 89 percent / benzoyl peroxide / acetonitrile / 3 h / 0 °C

With dmap; N-Bromosuccinimide; 4 A molecular sieve; ammonia; bromine; iodine; silver trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; triethylamine; pyridinium chlorochromate; tetramethylurea; calcium carbonate; hydroxylamine-O-sulfonic acid; dibenzoyl peroxide; In pyridine; tetrachloromethane; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0008-6215(96)00207-8

Reference yield:

: 14218-11-2,14218-30-5,61198-88-7,108438-33-1,108836-02-8,114682-36-9,127305-34-4,151377-77-4
2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide

: 186091-02-1
2-azi-1-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)-6-oxa-8-thianonane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) tetramethylurea, silver trifluoromethanesulfonate, 4A molecular sieves / 1.) CH₂Cl₂, rt, 1 h, 2.) CH₂Cl₂, -20 deg C, 4 h

2: 81 percent / N-bromosucinimide, CaCO₃, Br₂ / CCl₄; H₂O / 3 h / Ambient temperature

3: 89 percent / benzoyl peroxide / acetonitrile / 3 h / 0 °C

With N-Bromosuccinimide; 4 A molecular sieve; bromine; silver trifluoromethanesulfonate; tetramethylurea; calcium carbonate; dibenzoyl peroxide; In tetrachloromethane; water; acetonitrile;
DOI:10.1016/S0008-6215(96)00207-8