CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II) TETRAMER

Base Information

• Chemical Name: CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II) TETRAMER
• CAS No.: 113860-07-4
• Molecular Formula: C₂₇H₂₇N₇O₂S
• Molecular Weight: 513.623

Synonyms:1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-, ruthenium complex;Chloro(pentamethylcyclopentadienyl)ruthenium tetramer; Chloro(h5-pentamethylcyclopentadienyl)rutheniumtetramer; Tetra-m3-chlorotetrakis((h5-pentamethylcyclopentadienyl)ruthenium);Tetrachlorotetrakis(pentamethylcyclopentadienyl)tetraruthenium; Tetrachlorotetrakis(h5-pentamethylcyclopentadienyl)tetraruthenium;Tetrakis((m3-chloro)(h5-pentamethylcyclopentadienyl)ruthenium);Tetrakis(chloro(h5-pentamethylcyclopentadienyl)ruthenium);Tetrakis(m3-chloro)tetrakis((h5-pentamethylcyclopentadienyl)ruthenium);Tetrakis[m-chloro(h5-pentamethylcyclopentadienyl)ruthenium]

Chemical Property of CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II) TETRAMER

Chemical Property:

• Melting Point: 276-278 °C
• PSA: 0.00000
• LogP: 16.88510
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chloro(pentamethylcyclopentadienyl)ruthenium(II) Tetramer >95.0%(T) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II) TETRAMER

There total 6 articles about CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II) TETRAMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

ethyl 2-(4-methyl-1,4-diazepan-1-yl)-5-oxo-5H-benzo[4,5]thiazolo-[3,2-a][1,8]-naphthyridine-6-carboxylate (1138555-04-0) + (5-methylpyrazine-2-yl)methylamine (132664-85-8) → 2-(4-methyl-1,4-diazepan-1-yl)-N-((5-methylpyrazin-2-yl)methyl)-5-oxo-5H-benzo[4,5]thiazolo[3,2-a][1,8]naphthyridine-6-carboxamide (1138549-36-6)

Guidance literature:

With aluminum (III) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2010.12.108

Reference yield: 66.0%

C23H24N4O3S*ClH + (5-methylpyrazine-2-yl)methylamine (132664-85-8) → 2-(4-methyl-1,4-diazepan-1-yl)-N-((5-methylpyrazin-2-yl)methyl)-5-oxo-5H-benzo[4,5]thiazolo[3,2-a][1,8]naphthyridine-6-carboxamide (1138549-36-6)

Guidance literature:

C₂₃H₂₄N₄O₃S*ClH; In dichloromethane; at 30 ℃; for 0.166667h; Large scale;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 30 ℃; for 0.166667h; Large scale;

(5-methylpyrazine-2-yl)methylamine; Further stages; Large scale;

Reference yield:

ethyl 2-chloro-5-oxo-5H-benzo[4,5]thiazolo[3,2-a][1,8]naphthyridine-6-carboxylate (881633-93-8) → 2-(4-methyl-1,4-diazepan-1-yl)-N-((5-methylpyrazin-2-yl)methyl)-5-oxo-5H-benzo[4,5]thiazolo[3,2-a][1,8]naphthyridine-6-carboxamide (1138549-36-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: acetonitrile / 4 h / Reflux

2.1: aluminum (III) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.5 h / -5 - 5 °C

2.2: 1 h / -5 - 20 °C

With aluminum (III) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; acetonitrile;

DOI:10.1021/ml300110s

upstream raw materials:

ethyl 2-(4-methyl-1,4-diazepan-1-yl)-5-oxo-5H-benzo[4,5]thiazolo-[3,2-a][1,8]-naphthyridine-6-carboxylate

(5-methylpyrazine-2-yl)methylamine

ethyl 2-chloro-5-oxo-5H-benzo[4,5]thiazolo[3,2-a][1,8]naphthyridine-6-carboxylate

2,6-dichloropyridine-3-carboxylic acid

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