(+)-muricatacin

Base Information

Chemical Name:(+)-muricatacin
CAS No.:134699-11-9
Molecular Formula:C₁₇H₃₂O₃
Molecular Weight:284.439
Hs Code.:

Synonyms:(+)-muricatacin

Suppliers and Price of (+)-muricatacin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-muricatacin

Chemical Property:

Purity/Quality:

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Technology Process of (+)-muricatacin

There total 3 articles about (+)-muricatacin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 61550-02-5
(furan-2-yloxy)-trimethylsilane

: 10486-19-8
tridecanal

: 139396-45-5
(1’R,5S)-5-[1’-hydroxytridecyl]-3H,5H-furan-2-one

: 134699-11-9
(+)-muricatacin

Guidance literature:: With titanium(IV) isopropylate; hydrogen; (R)-1,1'-Bi-2-naphthol; palladium on activated charcoal; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, -20 deg C, 1.5 h, 2.) CH₂Cl₂, toluene, room temp., 12 h;
DOI:10.1021/jo9804137

Reference yield:

: 6064-48-8
1-hydroxy-2(E)-pentadecene

: 134699-11-9
(+)-muricatacin

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / MnO₂ / hexane / 24 h / 20 °C

2: 93 percent / 18-crown-6; t-BuOK / tetrahydrofuran / 2.5 h / -78 °C

3: OsO₄; MeSO₂NH₂; (DHQ)2PHAL / K₃Fe(CN)6; K₂CO₃ / 2-methyl-propan-2-ol; H₂O / 0 °C

4: 97 percent / H₂ / Pd/C / methanol / 24 h / 760 Torr

With manganese(IV) oxide; osmium(VIII) oxide; Hydroquinone 1,4-phthalazinediyl diether; 18-crown-6 ether; methanesulfonamide; potassium tert-butylate; hydrogen; palladium on activated charcoal; potassium carbonate; potassium hexacyanoferrate(III); In tetrahydrofuran; methanol; hexane; water; tert-butyl alcohol; 2: Still-Gennari reaction / 3: Sharpless asymmetric dihydroxylation;
DOI:10.1021/jo061057s

Reference yield:

: 2907-52-0,6064-48-8,36727-44-3
2-pentadecen-1-ol

: 134699-11-9
(+)-muricatacin

Guidance literature:: Multi-step reaction with 6 steps

1.1: titanium(IV) isopropylate; L-(+)-diisopropyl tartrate / dichloromethane / 0.5 h / -24 °C / Molecular sieve; Inert atmosphere

1.2: 4 h / -24 °C / Inert atmosphere

2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / Inert atmosphere

3.1: benzene / 1 h / Reflux; Inert atmosphere

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; boric acid / tetrahydrofuran / 0.17 h / 20 °C

5.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 3 h

6.1: toluene-4-sulfonic acid / methanol / 5 h / 20 °C

With titanium(IV) isopropylate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; palladium 10% on activated carbon; hydrogen; boric acid; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; benzene; 1.1: Katsuki-sharpless assymetric epoxidation / 1.2: Katsuki-sharpless assymetric epoxidation / 3.1: Wittig olefination;
DOI:10.2174/157017812801264656