methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Base Information

Chemical Name:methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate
CAS No.:107222-31-1
Molecular Formula:C₂₈H₃₀O₂
Molecular Weight:398.545
Hs Code.:

methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Synonyms:methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Suppliers and Price of methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

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Chemical Property of methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

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Technology Process of methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

There total 2 articles about methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 107201-24-1
methyl octadecahydro-7-benzyl-3-oxo-1H-cyclopenta<3,4>pentaleno-<2,1,6-gha>pentaleno<1,2,3-cd>pentalene-7-carboxylate

: 107222-31-1
methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Guidance literature:: With toluene-4-sulfonic acid; Yield given. Multistep reaction; 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h;
DOI:10.1021/jo00383a017

Reference yield:

: 100-44-7
benzyl chloride

: 107222-31-1
methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Li, NH₃ / 1.) 1,2-dimethoxyethane, -78 deg C, 30 min, 2.) 1,2-dimethoxyethane, a) -78 deg C, 30 min, b) -33 deg C, 30 min

2: 2.) p-toluenosulfonic acid / 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h

With ammonia; lithium; toluene-4-sulfonic acid;
DOI:10.1021/jo00383a017