C₃₆H₆₄O₄Si₃

Base Information

• Chemical Name: C₃₆H₆₄O₄Si₃
• CAS No.: 1350623-66-3
• Molecular Formula: C₃₆H₆₄O₄Si₃
• Molecular Weight: 645.158
• Mol file: 1350623-66-3.mol

Synonyms:C₃₆H₆₄O₄Si₃

Chemical Property of C₃₆H₆₄O₄Si₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₆₄O₄Si₃

There total 8 articles about C₃₆H₆₄O₄Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

C31H56O5Si2 (1350623-64-1) → C36H64O4Si3 (1350623-66-3)

Guidance literature:

With lithium trimethylsilylacetylenide; In tetrahydrofuran; hexane; at -78 ℃; for 0.883333h; Inert atmosphere;

DOI:10.1021/ol2028256

Reference yield: 77.0%

C36H66O5Si3 → C36H64O4Si3 (1350623-66-3)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 - 20 ℃; for 24h; Molecular sieve; Inert atmosphere;

DOI:10.1021/ol2028256

Reference yield:

1,2-dideoxy-3,6-di-O-triisopropylsilyl-2-deoxy-D-arabino-1-hexenopyranose (343338-29-4) → C36H64O4Si3 (1350623-66-3)

Guidance literature:

Multi-step reaction with 4 steps

1: tetra-(n-butyl)ammonium iodide; sodium hydride / N,N-dimethyl-formamide / 2.5 h / 0 °C / Inert atmosphere

2: triphenylphosphine hydrobromide / dichloromethane; water / 13.97 h / 0 - 20 °C

3: sodium acetate; pyridinium chlorochromate / dichloromethane / 1.5 h / 20 °C / Molecular sieve; Inert atmosphere

4: lithium trimethylsilylacetylenide / tetrahydrofuran; hexane / 0.88 h / -78 °C / Inert atmosphere

With lithium trimethylsilylacetylenide; sodium acetate; triphenylphosphine hydrobromide; tetra-(n-butyl)ammonium iodide; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; hexane; dichloromethane; water; N,N-dimethyl-formamide;

DOI:10.1021/ol2028256

upstream raw materials:

C₃₁H₅₆O₄Si₂

C₃₁H₅₆O₅Si₂

triisopropylsilyl chloride

D-glucal

Downstream raw materials:

C₂₈H₃₈O₅Si₂

C₂₁H₂₂O₅S₂

C₁₉H₂₀O₄

C₂₇H₄₄O₄Si₂