Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Base Information

Chemical Name:Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid
CAS No.:104039-80-7
Molecular Formula:C₄₃H₄₉N₃O₁₀
Molecular Weight:767.876
Hs Code.:

Synonyms:Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Suppliers and Price of Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

There total 7 articles about Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.6%

: Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-4,6-O-benzyliden-β-D-galactopyranosyl)-β-D-glucopyranosid

: 104039-80-7
Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Guidance literature:: With acetic acid; at 80 ℃; for 1h;
DOI:10.1016/S0008-6215(00)90670-0

Reference yield:

: 51450-24-9
hexa-O-acetyl-D-lactal

: 104039-80-7
Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Ce(NO₃)4*2NH₄NO₃, NaN₃, 2.) LiNO₃ / 2.) acetonitrile, DMF, 2 d, room temp.

2: 33 percent / Na / 0.25 h

3: 4.7 g / p-toluenesulfonic / acetonitrile / 3 h / Ambient temperature

4: 4.40 g / NaH / dimethylformamide / 2 h / Ambient temperature

5: 99.6 percent / 80percent acetic acid / 1 h / 80 °C

With ammonium nitrate; cerium nitrate; sodium azide; lithium nitrate; sodium; sodium hydride; toluene-4-sulfonic acid; acetic acid; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0008-6215(00)90670-0

Reference yield:

: 68733-24-4
O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl bromide

: 104039-80-7
Allyl-2-azido-3,6-di-O-benzyl-2-desoxy-4-O-(2,3-di-O-benzyl-β-D-galactopyranosyl)-β-D-glucopyranosid

Guidance literature:: Multi-step reaction with 5 steps

1: 58 percent / silversilicate, molecular sieve (4 Angstroem) / CH₂Cl₂; toluene / 1.) -15 deg C, 15 h, 2.) room temp., 2 d

2: 91 percent / NaOMe / methanol / 1 h

3: 4.7 g / p-toluenesulfonic / acetonitrile / 3 h / Ambient temperature

4: 4.40 g / NaH / dimethylformamide / 2 h / Ambient temperature

5: 99.6 percent / 80percent acetic acid / 1 h / 80 °C

With silversilicate; 4 A molecular sieve; sodium methylate; sodium hydride; toluene-4-sulfonic acid; acetic acid; In methanol; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1016/S0008-6215(00)90670-0