exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

Base Information

Chemical Name:exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine
CAS No.:134414-81-6
Molecular Formula:C₁₆H₂₀FNO₂S
Molecular Weight:309.405
Hs Code.:

Synonyms:exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

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Technology Process of exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

There total 5 articles about exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98-10-2
benzenesulfonamide

: 134414-81-6
exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / titanium tetrachloride / 1,1,2-trichloro-ethane; CH₂Cl₂ / 24 h / Heating

2: 1.) sodium bis(trimethylsilyl)amide (NaHMDS), 2.) perchloryl fluoride / 1.) THF, 0 deg C, 20 min, 2.) THF, 0 deg C, 15 min

With perchloryl fluoride; sodium hexamethyldisilazane; titanium tetrachloride; In dichloromethane; 1,1,2-trichloroethane;
DOI:10.1021/ja00030a045

Reference yield:

: 464-49-3,68546-28-1
(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 134414-81-6
exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / titanium tetrachloride / 1,1,2-trichloro-ethane; CH₂Cl₂ / 24 h / Heating

2: 1.) sodium bis(trimethylsilyl)amide (NaHMDS), 2.) perchloryl fluoride / 1.) THF, 0 deg C, 20 min, 2.) THF, 0 deg C, 15 min

With perchloryl fluoride; sodium hexamethyldisilazane; titanium tetrachloride; In dichloromethane; 1,1,2-trichloroethane;
DOI:10.1021/ja00030a045

Reference yield:

: 122270-25-1
(-)-N-(phenylsulfonyl)camphorimine

: 134414-81-6
exo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

: 134524-70-2
endo-(-)-N-(phenylsulfonyl)-3-fluorocamphorimine

Guidance literature:: With sodium hexamethyldisilazane; N-Fluoro-o-benzenedisulfonimide; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) THF, -78 deg C, 30 min, 2.) THF, 20 deg C, 4 h;
DOI:10.1021/ja00030a045