carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

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Chemical Name:carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester
CAS No.:355121-65-2
Molecular Formula:C₃₉H₅₄BrNO₈Si
Molecular Weight:772.849
Hs Code.:

Synonyms:carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

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Chemical Property of carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

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Technology Process of carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

There total 12 articles about carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 355121-64-1
4[(S)-2-(3,5-bis-allyloxy-4-bromo-benzylamino)-3-(triisopropyl-silanyloxy)-propyl]-phenol

: 2937-50-0
Allyl chloroformate

: 355121-65-2
carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 1.5h;
DOI:10.1021/ja016093h

Reference yield: 97.0%

: 355121-64-1
4[(S)-2-(3,5-bis-allyloxy-4-bromo-benzylamino)-3-(triisopropyl-silanyloxy)-propyl]-phenol

: 108-48-5
2,6-dimethylpyridine

aqueous ammonium chloride: aqueous ammonium chloride

: 2937-50-0
Allyl chloroformate

: 355121-65-2
carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

Guidance literature:: In dichloromethane;

Reference yield:

: 355121-59-4
(S)-2-allyloxycarbonylamino-3-(4-hydroxy-phenyl)-propionic acid methyl ester

: 355121-65-2
carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / K₂CO₃ / dimethylformamide / 9 h / 20 °C

2: 80 percent / lithium chloride; sodium borohydride; ethanol / tetrahydrofuran / 19 h / 20 °C

3: 88 percent / diisopropylethylamine / CH₂Cl₂ / 0 - 20 °C

4: morpholine / tetrahydrofuran / 10 h / 47 °C

5: 66 percent / acetic acid; sodium cyanoborohydride / methanol / 15 h / 20 °C

6: 97 percent / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 20 °C

With morpholine; 2,6-dimethylpyridine; sodium tetrahydroborate; ethanol; sodium cyanoborohydride; potassium carbonate; acetic acid; N-ethyl-N,N-diisopropylamine; lithium chloride; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja016093h