[chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)]

Base Information

• Chemical Name: [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)]
• CAS No.: 1376044-12-0
• Molecular Formula: C₂₅H₂₂ClFO₃Ru
• Molecular Weight: 525.969

Synonyms:[chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)]

Chemical Property of [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)]

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Technology Process of [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)]

There total 2 articles about [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η⁶-p-cymene)ruthenium(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

2-(4-fluorophenyl)-3-hydroxy-4-oxo-4H-1-benzopyran (364-56-7) + [RhCl2(p-cymene)]2 → [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η6-p-cymene)ruthenium(II)] (1376044-12-0)

Guidance literature:

With sodium methylate; In methanol; dichloromethane; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jm301376a

Reference yield: 60.0%

2-(4-fluorophenyl)-3-hydroxy-4-oxo-4H-1-benzopyran (364-56-7) + [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) → [chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η6-p-cymene)ruthenium(II)] (1376044-12-0)

Guidance literature:

2-(4-fluorophenyl)-3-hydroxy-4-oxo-4H-1-benzopyran; With lithium hexamethyldisilazane; In diethyl ether; at 20 ℃; for 3h; Glovebox; Inert atmosphere;

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In acetonitrile; Glovebox; Inert atmosphere;

DOI:10.1021/om5006337

Reference yield:

[chlorido{3-(oxo-κO)-2-(4-fluorophenyl)-chromen-4(1H)-onato-κO}(η6-p-cymene)ruthenium(II)] (1376044-12-0) + acetonitrile (75-05-8,26809-02-9) → C22H20FN4O4Ru(1+)*Cl(1-) + C23H20FN4O5Ru(1+)*Cl(1-) + C21H17FN3O5Ru(1+)*Cl(1-) + C23H20FN4O5Ru(1+)*C2H3N

Guidance literature:

With oxygen; for 12h; UV-irradiation;

DOI:10.1021/om5006337

upstream raw materials:

2-(4-fluorophenyl)-3-hydroxy-4-oxo-4H-1-benzopyran

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

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