2-(Cyclopropylidenemethyl)benzaldehyde

Base Information

Chemical Name:2-(Cyclopropylidenemethyl)benzaldehyde
CAS No.:111653-84-0
Molecular Formula:C11H10 O
Molecular Weight:158.1965
Hs Code.:
DSSTox Substance ID:DTXSID10549056
Nikkaji Number:J2.538.242K
Mol file:111653-84-0.mol

Synonyms:2-(Cyclopropylidenemethyl)benzaldehyde;111653-84-0;Benzaldehyde, 2-(cyclopropylidenemethyl)- (9CI);DTXSID10549056

Suppliers and Price of 2-(Cyclopropylidenemethyl)benzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of 2-(Cyclopropylidenemethyl)benzaldehyde

Chemical Property:

Boiling Point:95 °C(Press: 0.1 Torr)
PSA：17.07000
Density:1.192±0.06 g/cm3(Predicted)
LogP:2.67630
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:158.073164938
Heavy Atom Count:12
Complexity:199

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC1=CC2=CC=CC=C2C=O

Technology Process of 2-(Cyclopropylidenemethyl)benzaldehyde

There total 6 articles about 2-(Cyclopropylidenemethyl)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 111653-78-2
o-(1,3-dioxolan-2-yl)benzylidenecyclopropane

: 111653-84-0
2-(cyclopropylidenemethyl)benzaldehyde

Guidance literature:: With water; silica gel; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1039/P19870000913

Reference yield: 62.0%

: 864910-02-1
1-(cyclopropylidenemethyl)-2-bromobenzene

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 111653-84-0
2-(cyclopropylidenemethyl)benzaldehyde

Guidance literature:: 1-bromo-2-(cyclopropylidenemethyl)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
DOI:10.1002/chem.202001223

Reference yield: 50.0%

: 14114-05-7
cyclopropyltriphenylphosphonium bromide

: 643-79-8
o-phthalic dicarboxaldehyde

: 111653-84-0
2-(cyclopropylidenemethyl)benzaldehyde

Guidance literature:: cyclopropyltriphenylphosphonium bromide; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

o-phthalic dicarboxaldehyde; In tetrahydrofuran; for 6h; Inert atmosphere; Reflux;
DOI:10.1021/acs.joc.0c00090