(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

Base Information

Chemical Name:(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester
CAS No.:164215-48-9
Molecular Formula:C₃₉H₆₀O₁₂Si
Molecular Weight:748.984
Hs Code.:

(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

Synonyms:(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

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Chemical Property of (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

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Technology Process of (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

There total 22 articles about (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 164215-43-4
(1S,3R,4S,5R,6R,7R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-1-((4R,5R)-4-hydroxy-5-methyl-6-phenyl-hexyl)-2,8-dioxa-bicyclo[3.2.1]octane-4,6,7-triol

: 164215-48-9
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / 4-DMAP / CH₂Cl₂ / 12 h

2: 90 percent / Cl₂CHCO₂H / methanol / 7 h

3: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

4: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

5: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

6: CH₂Cl₂ / 22 h

With dichloro-acetic acid; dmap; sodium chlorite; hydrogen; Dess-Martin periodane; palladium on activated charcoal; In pyridine; methanol; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008

Reference yield:

: 164215-45-6
Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-4-hydroxy-3-hydroxymethyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

: 164215-48-9
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

2: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

3: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

4: CH₂Cl₂ / 22 h

With sodium chlorite; hydrogen; Dess-Martin periodane; palladium on activated charcoal; In pyridine; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008

Reference yield:

: 164215-44-5
Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-4-ethynyl-4-hydroxy-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

: 164215-48-9
(1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 90 percent / Cl₂CHCO₂H / methanol / 7 h

2: H₂ / 5percent Pd/C / pyridine / 2 h / 760 Torr

3: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 23 °C

4: aq. NaClO₂ / 2-methyl-propan-2-ol; various solvent(s) / 3 h / 10 °C

5: CH₂Cl₂ / 22 h

With dichloro-acetic acid; sodium chlorite; hydrogen; Dess-Martin periodane; palladium on activated charcoal; In pyridine; methanol; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja00136a008