alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate

Base Information

Chemical Name:alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate
CAS No.:117300-00-2
Molecular Formula:C₂₄H₃₀O₇
Molecular Weight:430.498
Hs Code.:
DSSTox Substance ID:DTXSID701155902

Synonyms:DTXSID701155902;alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate;117300-00-2

Suppliers and Price of alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:11
Exact Mass:430.19915329
Heavy Atom Count:31
Complexity:516

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OC1C(C(C(C(O1)COC)OCC2=CC=CC=C2)OCC3=CC=CC=C3)OC
Isomeric SMILES:CC(=O)O[C@@H]1[C@H]([C@H]([C@@H]([C@H](O1)COC)OCC2=CC=CC=C2)OCC3=CC=CC=C3)OC

Technology Process of alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate

There total 1 articles about alpha-D-Mannopyranose, 2,6-di-O-methyl-3,4-bis-O-(phenylmethyl)-, acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.3%

: 108-24-7
acetic anhydride

: 117299-99-7
methyl 3,4-di-O-benzyl-2,6-di-O-methyl-α-D-mannopyranoside

: 117300-00-2
Acetic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-3-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl ester

Guidance literature:: With sulfuric acid; In acetic acid; at 0 ℃; for 1h;
DOI:10.1016/0008-6215(88)85085-7

Reference yield: 95.2%

: 117300-00-2
Acetic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-3-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl ester

: 117325-10-7
3,4-di-O-benzyl-2,6-di-O-methyl-α-D-mannopyranosyl chloride

Guidance literature:: With Dichloromethyl methyl ether; 4 A molecular sieve; zinc(II) chloride; In dichloromethane; at -10 ℃; for 1h;
DOI:10.1016/0008-6215(88)85085-7

Reference yield:

: 117300-00-2
Acetic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-3-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl ester

: 117300-02-4,117405-68-2
3,4-di-O-benzyl-2-O-methyl-α-L-lyxopyranosyl 3,4-di-O-benzyl-2,6-di-O-methyl-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 95.2 percent / ZnCl₂, dichloromethyl methyl ether, molecular sieves 4 A / CH₂Cl₂ / 1 h / -10 °C

2: molecular sieves 4 A / silver zeolite / CH₂Cl₂ / 24 h / dark

With Dichloromethyl methyl ether; 4 A molecular sieve; zinc(II) chloride; silver zeolite; In dichloromethane;
DOI:10.1016/0008-6215(88)85085-7