IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Base Information

• Chemical Name: IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)
• CAS No.: 88035-05-6
• Molecular Formula: C₂₇H₂₆IIrOP₂
• Molecular Weight: 747.575
• Mol file: 88035-05-6.mol

Synonyms:IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Chemical Property of IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

There total 2 articles about IrH₂I(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

IrI(CO)(1,2-bis(diphenylphosphino)ethane) (85421-68-7) → [(CO)IrH2I((C6H5)2PCH2CH2P(C6H5)2)] + IrH2I(CO)((C6H5)2PCH2CH2P(C6H5)2) (88035-05-6)

Guidance literature:

With hydrogen; In benzene; at 25°C;

DOI:10.1021/ja00364a066

Reference yield:

IrI(CO)((C6H5)2PCH2CH2P(C6H5)2) (85421-68-7) → IrH2I(CO)((C6H5)2PCH2CH2P(C6H5)2) (88035-05-6)

Guidance literature:

With hydrogen; In tetrahydrofuran; ethanol; modified Schlenk techniques; dissoln. of Ir-complex in THF under H2, stirring until soln. becomes orange (<= 3 min), addn. of EtOH, bubbling ofH2 through soln. for several hours until product ppts. (colorless);

Reference yield:

IrH2I(CO)((C6H5)2PCH2CH2P(C6H5)2) (88035-05-6) → IrI(CO)2((C6H5)2PCH2CH2P(C6H5)2) (85421-70-1)

Guidance literature:

With CO; In benzene; Ir complex placed in NMR tube, C6H6 condensed at - 196°C, exposed to 600 torr CO, after flame-sealing thawed, shaken for 1 min, left at 25°C; not isolated, monitored by NMR; Kinetics;

DOI:10.1021/ja00297a021

upstream raw materials:

IrI(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)

IrI(CO)(1,2-bis(diphenylphosphino)ethane)

Downstream raw materials:

IrI(CO)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)