(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

Base Information

Chemical Name:(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane
CAS No.:1050206-92-2
Molecular Formula:C₃₅H₄₀F₃NO₅Si
Molecular Weight:639.787
Hs Code.:

(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

Synonyms:(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

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Chemical Property of (1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

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Technology Process of (1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

There total 1 articles about (1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1050207-08-3
C₃₃H₄₁NO₄Si

: 407-25-0
trifluoroacetic anhydride

: 1050206-92-2
(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

Guidance literature:: C₃₃H₄₁NO₄Si; trifluoroacetic anhydride; With pyridine; at 0 ℃; for 1.5h;

With toluene-4-sulfonic acid; In acetone; for 90h; Further stages.;
DOI:10.1016/j.tet.2008.05.096

Reference yield: 64.0%

: 1050206-92-2
(1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane

: 108-24-7
acetic anhydride

: 407-25-0
trifluoroacetic anhydride

: (1R,3R,4R,5R)-1-(p-trifluoroacetylaminophenyl)-3-(tert-butyldiphenylsilyloxymethyl)-4,7-diacetoxy-2,6-dioxabicyclo[3.3.0]octane

Guidance literature:: (1R,5R,6S,8R)-3,3-dimethyl-6-(p-trifluoroacetylaminophenyl)-6-(2'-propenyl)-8-(tert-butyldiphenylsilyloxymethyl)-2,4,7-trioxabicyclo[3.3.0]octane; trifluoroacetic anhydride; With pyridine; sodium periodate; osmium(VIII) oxide; at 20 ℃;

With sulfuric acid; In tetrahydrofuran; at 60 ℃;

acetic anhydride; With pyridine; at 20 ℃; Further stages.;
DOI:10.1016/j.tet.2008.05.096