phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

Base Information

Chemical Name:phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside
CAS No.:261374-43-0
Molecular Formula:C₂₁H₃₂O₈S
Molecular Weight:444.546
Hs Code.:

Synonyms:phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

Suppliers and Price of phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

There total 1 articles about phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 170451-44-2
phenyl 3-O-[4-O-(tert-butyldimethylsilyl)-2,3-di-O-methyl-α-L-fucopyranosyl]-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

: 261374-43-0
phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 48h;
DOI:10.1021/ja993487o

Reference yield:

: 261374-43-0
phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

: 223693-28-5
(1S,4R,5R,7R,9R,13S,14S,15S)-4-hydroxy-9-[(E)-2-iodovinyl]-15-[[3-O-[4-O-(p-methoxybenzyl)-2,3-di-O-methyl-α-L-fucopyranosyl]-2,4-di-O-methyl-β-D-xylopyranosyl]oxy]-5,8,8,14-tetramethyl-10,17,18-trioxatricyclo[11.3.1.1^4,7]octadecane-3,11-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / NaI; NaH / tetrahydrofuran / 0.5 h / 65 °C

2: 36 percent / NBS; 4A MS / acetonitrile

With N-Bromosuccinimide; sodium hydride; sodium iodide; In tetrahydrofuran; acetonitrile; 1: benzylation / 2: Nicolaou glycosidation;
DOI:10.1021/ja993487o

Reference yield:

: 261374-43-0
phenyl 3-O-(2,3-di-O-methyl-α-L-fucopyranosyl)-2,4-di-O-methyl-1-thio-β-D-xylopyranoside

: (1S,4R,5R,7R,9R,13S,14S,15S)-4-hydroxy-9-[(E)-2-iodovinyl]-15-[[3-O-[4-O-(p-methoxybenzyl)-2,3-di-O-methyl-α-L-fucopyranosyl]-2,4-di-O-methyl-α-D-xylopyranosyl]oxy]-5,8,8,14-tetramethyl-10,17,18-trioxatricyclo[11.3.1.1^4,7]octadecane-3,11-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / NaI; NaH / tetrahydrofuran / 0.5 h / 65 °C

2: 13 percent / NBS; 4A MS / acetonitrile

With N-Bromosuccinimide; sodium hydride; sodium iodide; In tetrahydrofuran; acetonitrile; 1: benzylation / 2: Nicolaou glycosidation;
DOI:10.1021/ja993487o