(-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE

Base Information

Chemical Name:(-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE
CAS No.:111137-94-1
Molecular Formula:C₄₃H₃₈O₆P₂
Molecular Weight:712.719
Hs Code.:
Mol file:111137-94-1.mol

Synonyms:b-D-Glucopyranoside, phenyl4,6-O-(phenylmethylene)-, bis(diphenylphosphinite), (R)-;Pyrano[3,2-d]-1,3-dioxin, b-D-glucopyranoside deriv.

Suppliers and Price of (-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
R-(-)-[4-PHENYL-6-O-BENZYLIDENEBIS(DIPHENYLPHOSPHINITE)]-BETA-D-GLUCOPYRANOSIDE 95.00%
5MG
$ 503.72

Total 2 raw suppliers

Chemical Property of (-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE

Chemical Property:

Boiling Point:794.7±70.0 °C(Predicted)
PSA：82.56000
LogP:7.77070

Purity/Quality:

98%min ^*data from raw suppliers

R-(-)-[4-PHENYL-6-O-BENZYLIDENEBIS(DIPHENYLPHOSPHINITE)]-BETA-D-GLUCOPYRANOSIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE

There total 2 articles about (-)-PHENYL-4,6-O-(R)-BENZYLIDENE-2,3-O-BIS-(DIPHENYLPHOSPHINO)-BETA-D-GLUCOPYRANOSIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 117677-62-0
phenyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside

: 76313-27-4,111137-94-1,111137-96-3,117677-63-1
phenyl 4,6-O-benzylidene-2,3-O-bis(diphenylphosphino)-β-D-galactopyranoside

Guidance literature:: With pyridine; for 2h;

Reference yield:

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 22887-10-1,42821-94-3,54502-82-8,57783-84-3,61169-05-9,61169-06-0,61221-61-2,75829-66-2,111137-95-2,117677-62-0
phenyl 4,6-O-benzylidene-β-D-glucopyranoside

: 111137-94-1
phenyl 4,6-O-(R)-benzylidene-2,3-O-bis(diphenylphosphino)-β-D-glucopyranoside

Guidance literature:: With dmap; In toluene;
DOI:10.1021/ol062002f

Reference yield: 70.8%

: 111137-94-1
phenyl 4,6-O-(R)-benzylidene-2,3-O-bis(diphenylphosphino)-β-D-glucopyranoside

: acethylacetonato(1,5-cyclooctadiene)rhodium(I)

: 125669-90-1
{rhodium(phenyl 2,3-O-bis(diphenylphosphino)-β-D-glucopyranoside)(Z,Z-cycloocta-1,5-diene)}HSO4

Guidance literature:: With sulfuric acid; In tetrahydrofuran; anaerobic and anhydrous conditions; 70% aq. H2SO4;; solidified after 4 d at room temp. and 2 d in the refrigerator; filtered; washed with THF, THF/Et2O 1/1 and Et2O; elem. anal.;;
DOI:10.1016/0022-328X(89)87287-0