(1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane

Base Information

Chemical Name:(1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane
CAS No.:75044-23-4
Molecular Formula:C₁₁H₁₆
Molecular Weight:148.248
Hs Code.:
Mol file:75044-23-4.mol

Synonyms:Cyclopropane,1-ethenyl-2-(1,3-hexadienyl)-, [1R-[1a,2a(1E,3Z)]]-; Cyclopropane, 1-ethenyl-2-(1E,3Z)-1,3-hexadienyl-, (1R,2S)-(9CI); Dictyopterene D

Suppliers and Price of (1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane

Chemical Property:

PSA：0.00000
LogP:3.33090

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane

There total 24 articles about (1R)-1α-Ethenyl-2α-[(1E,3Z)-1,3-hexadienyl]cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 132565-81-2,132565-85-6
Phosphoric acid diethyl ester (3Z,6Z)-1-vinyl-nona-3,6-dienyl ester

: 29837-19-2
(3E,5Z,8Z)-1,3,5,8-undecatetraene

: 50277-31-1
(3E,5E,8Z)-1,3,5,8-Undecatetraen

: 29837-20-5,33967-69-0,50265-44-6,50265-46-8,50265-58-2,69575-73-1,69575-74-2,74709-22-1,75044-23-4,77210-41-4,77255-13-1,99438-20-7,99438-21-8,103833-89-2
(+/-)-dictyopterene

Guidance literature:: With potassium hexamethylsilazane; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, -78 deg C, 2.) 0 deg C, 8 h;
DOI:10.1021/ja00006a066

Reference yield:

: 69508-34-5,69651-13-4,74709-21-0,74709-23-2
3-<(E,Z)-1,3-hexadienyl>-5-vinyl-1-pyrazoline

: 34048-44-7,52589-18-1
Ectocarpene

: 29837-20-5,33967-69-0,50265-44-6,50265-46-8,50265-58-2,69575-73-1,69575-74-2,74709-22-1,75044-23-4,77210-41-4,77255-13-1,99438-20-7,99438-21-8,103833-89-2
(+/-)-dictyopterene

Guidance literature:: for 12h; under 0.05 Torr; Yield given. Yields of byproduct given; Ambient temperature;
DOI:10.1021/ja00539a024

Reference yield:

: 4949-20-6,52192-01-5
(E)-2,4-pentadien-1-ol

: 29837-20-5,33967-69-0,50265-44-6,50265-46-8,50265-58-2,69575-73-1,69575-74-2,74709-22-1,75044-23-4,77210-41-4,77255-13-1,99438-20-7,99438-21-8,103833-89-2
(+/-)-dictyopterene

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 1.5 h

2: 1.) sodium bis(trimethylsilyl)amide / 1.) n-hexane, reflux, 3 h, 2.) THF, -78 deg C, 1.5 h; warm to ambient temperature

3: 55 percent Turnov_. / 72 h / 4 °C

4: pentane / 6 h / 15 °C / Irradiation

With sodium acetate; sodium hexamethyldisilazane; pyridinium chlorochromate; In dichloromethane; pentane;
DOI:10.1021/ja00539a024