methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate

Base Information

• Chemical Name: methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate
• CAS No.: 1013632-23-9
• Molecular Formula: C₂₁H₂₄N₂O₄S₃
• Molecular Weight: 464.631
• Mol file: 1013632-23-9.mol

Synonyms:methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate

Chemical Property of methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate

Chemical Property:

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Technology Process of methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate

There total 1 articles about methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(toluene-4-sulfonyl)-piperidine-4-carbonyl chloride (862421-68-9) + methyl hydroxy(phenyl)carbamodithioate (1013632-21-7) → methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate (1013632-23-9)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; Darkness;

DOI:10.1021/ol702832x

Reference yield: 86.0%

methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate (1013632-23-9) → 4-bromo-1-tosylpiperidine (347885-68-1)

Guidance literature:

With Bromotrichloromethane; In dichloromethane; at 5 ℃; for 4h; Sunlight irradiation;

DOI:10.1021/ol702832x

Reference yield: 84.0%

methyl phenyl(1-tosylpiperidine-4-carbonyloxy)carbamodithioate (1013632-23-9) → methyl 1-tosylpiperidin-4-yl phenylcarbonimidodithioate (1013632-27-3)

Guidance literature:

In dichloromethane; at 5 ℃; for 2h; Sunlight irradiation;

DOI:10.1021/ol702832x

upstream raw materials:

1-(toluene-4-sulfonyl)-piperidine-4-carbonyl chloride

methyl hydroxy(phenyl)carbamodithioate

Downstream raw materials:

methyl 1-tosylpiperidin-4-yl phenylcarbonimidodithioate

4-bromo-1-tosylpiperidine