methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside
CAS No.:1256137-54-8
Molecular Formula:C₂₂H₃₂N₂O₇Si
Molecular Weight:464.591
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

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Technology Process of methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

There total 4 articles about methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1256137-59-3
C₂₂H₃₃BrO₇Si

: 1256137-54-8
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: With N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 0 ℃; for 0.75h; Inert atmosphere;
DOI:10.1021/ja1054065

Reference yield:

: methyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

: 1256137-54-8
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / dichloromethane / 0.42 h / 0 °C / Inert atmosphere

2: N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 0 °C / Inert atmosphere

With pyridine; N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1080/07328303.2011.614983

Reference yield:

: 3162-96-7,4148-58-7,4153-17-7,4288-93-1,5328-47-2,6988-39-2,13566-32-0,14155-23-8,27994-50-9,37093-57-5,37093-59-7,57701-27-6,59168-66-0,64552-06-3,65391-13-1,65391-14-2,65530-26-9,66512-65-0,71117-36-7,71117-37-8,71117-41-4,72904-85-9,74560-56-8,79549-74-9,86783-81-5,96093-51-5,98633-13-7,110415-35-5,110415-36-6,110850-29-8,124020-29-7,126924-12-7,129263-21-4,131433-03-9,145920-49-6,146863-04-9
methyl-4,6-O-phenylmethylene-α-D-mannopyranoside

: 1256137-54-8
methyl 4,6-O-benzylidene-2-O-diazoacetyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane; N,N-dimethyl-formamide / 1.5 h / -20 °C / Inert atmosphere

2: pyridine / dichloromethane / 0.42 h / 0 °C / Inert atmosphere

3: N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 0 °C / Inert atmosphere

With pyridine; N,N'-ditosylhydrazine; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1080/07328303.2011.614983