(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

Base Information

Chemical Name:(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol
CAS No.:200704-89-8
Molecular Formula:C₂₃H₃₄O₃
Molecular Weight:358.521
Hs Code.:

Synonyms:(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

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Chemical Property of (E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

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Technology Process of (E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

There total 1 articles about (E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 200704-88-7
(E)-(1S,2R)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-one

: 200704-89-8
(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 1h;
DOI:10.1021/jo971592f

Reference yield:

: 3970-21-6
2-Methoxyethoxymethyl chloride

: 200704-89-8
(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

: 200704-99-0
(E)-(6S,7R,8S)-7-(4-Methoxy-benzyloxy)-6-(2-methoxy-ethoxymethoxy)-5,5,11,11-tetramethyl-bicyclo[6.2.1]undec-1-ene

Guidance literature:: With tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 60 ℃; for 4h;
DOI:10.1021/jo971592f

Reference yield:

: 200704-89-8
(E)-(1S,2R,3S)-2-(4-Methoxy-benzyloxy)-4,4,11,11-tetramethyl-bicyclo[6.2.1]undec-7-en-3-ol

: 200704-90-1
(1S,2S,6S,7R,8S)-7-(4-Methoxy-benzyloxy)-6-(2-methoxy-ethoxymethoxy)-5,5,11,11-tetramethyl-bicyclo[6.2.1]undecane-1,2-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 3.15 g / diisopropylethylamine, tetra-n-butylammonium iodide / dimethylformamide / 4 h / 60 °C

2: 1.) pyridine, osmium tetraoxide, 2.) NaHSO₃ / 1.) room temperature, 1.5 h, 2.) overnight

With pyridine; osmium(VIII) oxide; tetra-(n-butyl)ammonium iodide; sodium hydrogensulfite; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide;
DOI:10.1021/jo971592f