HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl]

Base Information

• Chemical Name: HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl]
• CAS No.: 177778-11-9
• Molecular Formula: C₆H₁₆N*C₂₄H₁₂F₁₅N₄*Cl*V
• Molecular Weight: 829.956
• Mol file: 177778-11-9.mol

Synonyms:HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl]

Chemical Property of HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl]

There total 1 articles about HN(C₂H₅)3⁽¹⁺⁾*V⁽³⁺⁾*N(CH₂CH₂NC₆F₅)3^(3-)*Cl^(1-)=[HN(C₂H₅)3][(N(CH₂CH₂NC₆F₅)3)VCl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9) + triethylamine (121-44-8) + 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine (155019-77-5) → HN(C2H5)3(1+)*V(3+)*N(CH2CH2NC6F5)3(3-)*Cl(1-)=[HN(C2H5)3][(N(CH2CH2NC6F5)3)VCl] (177778-11-9)

Guidance literature:

In diethyl ether; N2-atmosphere; addn. of mixt. of ligand and Et3N to V-complex (-30°C, over 1 h), slow warming to room temp., stirring for 1 d; filtration (Celite), concn., crystn. (-30°C, several d), washing (cold pentane), recrystn. (CH2Cl2, -30°C, several d), decantation, washing (cold ether), drying (vac.); elem. anal.;

DOI:10.1021/ic951433j

Reference yield: 95.0%

HN(C2H5)3(1+)*V(3+)*N(CH2CH2NC6F5)3(3-)*Cl(1-)=[HN(C2H5)3][(N(CH2CH2NC6F5)3)VCl] (177778-11-9) → V(4+)*Cl(1-)*N(CH2CH2NC6F5)3(3-)=VCl(N(CH2CH2NC6F5)3) (177778-19-7)

Guidance literature:

With ((C₅H₅)2Fe)(CF₃SO₃); In dichloromethane; N2-atmosphere; slight excess oxidant, warming from -30°C to room temp., stirring for 20 h; filtration (Celite), evapn. (vac.), dissoln. in PhMe, crystn. (-30°C, overnight), recrystn. (CH2Cl2, -30°C), washing (cold PhMe), drying (vac.); elem. anal.;

DOI:10.1021/ic951433j

Reference yield: 65.0%

HN(C2H5)3(1+)*V(3+)*N(CH2CH2NC6F5)3(3-)*Cl(1-)=[HN(C2H5)3][(N(CH2CH2NC6F5)3)VCl] (177778-11-9) + acetonitrile (75-05-8,26809-02-9) → (N(CH2CH2NC6F5)3)V(CH3CN) (177778-12-0)

Guidance literature:

In diethyl ether; acetonitrile; N2-atmosphere; stirring in ether/MeCN=7:1 v/v at room temp. for >= 3 h; solvent removal (vac.), extn. into cold ether, solvent removal (vac.), dissoln. in MeCN, layering with pentane, crystn. (-30°C; two crops), decantation, washing (cold pentane), drying (vac.); elem. anal.;

DOI:10.1021/ic951433j

upstream raw materials:

Vanadium (III) chloride-(tris-tetrahydrofuran)

triethylamine

2,2',2''-tris<(pentafluorophenyl)amino>triethylamine

Downstream raw materials:

V(N(CH₂CH₂NC₆F₅)3)(C₄H₈O)

V⁽⁴⁺⁾*Cl^(1-)*N(CH₂CH₂NC₆F₅)3^(3-)=VCl(N(CH₂CH₂NC₆F₅)3)

(N(CH₂CH₂NC₆F₅)3)V(CH₃CN)