C₇₂H₁₂₈INO₈Si₄

Base Information

Chemical Name:C₇₂H₁₂₈INO₈Si₄
CAS No.:148933-55-5
Molecular Formula:C₇₂H₁₂₈INO₈Si₄
Molecular Weight:1375.06
Hs Code.:

C<sub>72</sub>H<sub>128</sub>INO<sub>8</sub>Si<sub>4</sub>

Synonyms:C₇₂H₁₂₈INO₈Si₄

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Chemical Property of C₇₂H₁₂₈INO₈Si₄

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Technology Process of C₇₂H₁₂₈INO₈Si₄

There total 56 articles about C₇₂H₁₂₈INO₈Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 128209-97-2
(1R,3R,4R)-4-[(tert-butyldimethylsilyl)oxy]-3-methoxycyclohexane-1-carbaldehyde

: 148933-55-5
C₇₂H₁₂₈INO₈Si₄

Guidance literature:: Multi-step reaction with 14 steps

1: 95 percent / LiCl, (i-Pr)2NEt / acetonitrile / 1.) 25 deg C, 15 min, 2.) 25 deg C, 6 h

2: Et₃SiH / Rh(PPh₃)3Cl / 2 h / 50 °C

3: 49percent aq. HF / acetonitrile / 3 h / 25 °C

4: imidazole / dimethylformamide / 16 h / 25 °C

6: 98 percent / aq. LiBH₄ / diethyl ether; tetrahydrofuran / 1 h / 25 °C

7: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 24 h / 25 °C

8: 91 percent / LiEt₃BH / tetrahydrofuran / 2.5 h / 25 °C

9: 85 percent / 4-pyrrolidinopyridine, (i-Pr)2NEt, 1,3-diisopropylcarbodiimide / CH₂Cl₂ / 24 h / -20 °C

10: aq. 4-methylmorpholine-N-oxide, OsO₄ / acetone / 16 h / 25 °C

11: Pb(OAc)4, Na₂CO₃ / benzene / 1.5 h / 25 °C

12: 94 percent / CrCl₂ / tetrahydrofuran; dioxane / 1.5 h / 25 °C

13: 94 percent / DDQ, H₂O / CHCl₃ / 1 h / 25 °C

14: 1.) 2,6-lutidine , 2.) SiO₂ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 25 deg C, 16 h

With 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; lead(IV) acetate; triethylsilane; dmap; osmium(VIII) oxide; lithium borohydride; hydrogen fluoride; water; silica gel; lithium triethylborohydride; sodium carbonate; 4-pyrrolidin-1-ylpyridine; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; diisopropyl-carbodiimide; Wilkinson's catalyst; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;

Reference yield:

: 148933-83-9
(1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanol

: 148933-55-5
C₇₂H₁₂₈INO₈Si₄

Guidance literature:: Multi-step reaction with 22 steps

1: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) r.t., 2 h

2: LDA / tetrahydrofuran; hexane / 1.) -78 deg C, 15 min, 2.) 25 deg C, 2 h

3: Pd(OAc)2 / acetonitrile / 24 h / 50 °C

4: 95 percent / LiBH₄, CeCl₃*7H₂O / tetrahydrofuran; methanol / 1 h / -78 °C

5: 2.) LiEt₃BH / 1.) xylene, reflux, 48 h, 2.) THF, r.t., 2 h

6: 100 percent / H₂ / 10percent Pd/C / ethanol / 16 h / 25 °C

7: 1.) o-O₂NC₆H₄SeCN, n-Bu₃P, 2.) 30percent aq. H₂O₂ / 1.) THF, 25 deg C, 3 h, 2.) THF, 25 deg C, 6 h

8: 1.) O₃, 2.) Me₂S / 1.) CH₂Cl₂, MeOH, -78 deg C, 2.) 25 deg C, overnight

9: 95 percent / LiCl, (i-Pr)2NEt / acetonitrile / 1.) 25 deg C, 15 min, 2.) 25 deg C, 6 h

10: Et₃SiH / Rh(PPh₃)3Cl / 2 h / 50 °C

11: 49percent aq. HF / acetonitrile / 3 h / 25 °C

12: imidazole / dimethylformamide / 16 h / 25 °C

14: 98 percent / aq. LiBH₄ / diethyl ether; tetrahydrofuran / 1 h / 25 °C

15: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 24 h / 25 °C

16: 91 percent / LiEt₃BH / tetrahydrofuran / 2.5 h / 25 °C

17: 85 percent / 4-pyrrolidinopyridine, (i-Pr)2NEt, 1,3-diisopropylcarbodiimide / CH₂Cl₂ / 24 h / -20 °C

18: aq. 4-methylmorpholine-N-oxide, OsO₄ / acetone / 16 h / 25 °C

19: Pb(OAc)4, Na₂CO₃ / benzene / 1.5 h / 25 °C

20: 94 percent / CrCl₂ / tetrahydrofuran; dioxane / 1.5 h / 25 °C

21: 94 percent / DDQ, H₂O / CHCl₃ / 1 h / 25 °C

22: 1.) 2,6-lutidine , 2.) SiO₂ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 25 deg C, 16 h

With 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; lead(IV) acetate; triethylsilane; dmap; palladium diacetate; osmium(VIII) oxide; lithium borohydride; ortho-nitrophenyl selenocyanate; cerium(III) chloride; oxalyl dichloride; dimethylsulfide; tributylphosphine; hydrogen fluoride; water; hydrogen; dihydrogen peroxide; silica gel; lithium triethylborohydride; sodium carbonate; 4-pyrrolidin-1-ylpyridine; ozone; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; diisopropyl-carbodiimide; lithium diisopropyl amide; palladium on activated charcoal; Wilkinson's catalyst; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; ethanol; hexane; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;

Reference yield:

: (1S,2R,6S)-2-(benzyloxy)-7-oxabicyclo[4.1.0]heptane

: 148933-55-5
C₇₂H₁₂₈INO₈Si₄

Guidance literature:: Multi-step reaction with 25 steps

1: 90 percent / CSA / 2 h / 25 °C

2: 91 percent / 2,6-lutidine / CH₂Cl₂ / 1.5 h / 0 °C

3: 98 percent / H₂ / 10percent Pd/C / ethanol / 24 h / 25 °C

4: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) r.t., 2 h

5: LDA / tetrahydrofuran; hexane / 1.) -78 deg C, 15 min, 2.) 25 deg C, 2 h

6: Pd(OAc)2 / acetonitrile / 24 h / 50 °C

7: 95 percent / LiBH₄, CeCl₃*7H₂O / tetrahydrofuran; methanol / 1 h / -78 °C

8: 2.) LiEt₃BH / 1.) xylene, reflux, 48 h, 2.) THF, r.t., 2 h

9: 100 percent / H₂ / 10percent Pd/C / ethanol / 16 h / 25 °C

10: 1.) o-O₂NC₆H₄SeCN, n-Bu₃P, 2.) 30percent aq. H₂O₂ / 1.) THF, 25 deg C, 3 h, 2.) THF, 25 deg C, 6 h

11: 1.) O₃, 2.) Me₂S / 1.) CH₂Cl₂, MeOH, -78 deg C, 2.) 25 deg C, overnight

12: 95 percent / LiCl, (i-Pr)2NEt / acetonitrile / 1.) 25 deg C, 15 min, 2.) 25 deg C, 6 h

13: Et₃SiH / Rh(PPh₃)3Cl / 2 h / 50 °C

14: 49percent aq. HF / acetonitrile / 3 h / 25 °C

15: imidazole / dimethylformamide / 16 h / 25 °C

17: 98 percent / aq. LiBH₄ / diethyl ether; tetrahydrofuran / 1 h / 25 °C

18: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 24 h / 25 °C

19: 91 percent / LiEt₃BH / tetrahydrofuran / 2.5 h / 25 °C

20: 85 percent / 4-pyrrolidinopyridine, (i-Pr)2NEt, 1,3-diisopropylcarbodiimide / CH₂Cl₂ / 24 h / -20 °C

21: aq. 4-methylmorpholine-N-oxide, OsO₄ / acetone / 16 h / 25 °C

22: Pb(OAc)4, Na₂CO₃ / benzene / 1.5 h / 25 °C

23: 94 percent / CrCl₂ / tetrahydrofuran; dioxane / 1.5 h / 25 °C

24: 94 percent / DDQ, H₂O / CHCl₃ / 1 h / 25 °C

25: 1.) 2,6-lutidine , 2.) SiO₂ / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) 25 deg C, 16 h

With 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; lead(IV) acetate; triethylsilane; dmap; palladium diacetate; osmium(VIII) oxide; lithium borohydride; ortho-nitrophenyl selenocyanate; cerium(III) chloride; oxalyl dichloride; dimethylsulfide; tributylphosphine; camphor-10-sulfonic acid; hydrogen fluoride; water; hydrogen; dihydrogen peroxide; silica gel; lithium triethylborohydride; sodium carbonate; 4-pyrrolidin-1-ylpyridine; ozone; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; diisopropyl-carbodiimide; lithium diisopropyl amide; palladium on activated charcoal; Wilkinson's catalyst; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; ethanol; hexane; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;