diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

Base Information

Chemical Name:diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate
CAS No.:1193390-73-6
Molecular Formula:C₄₅H₅₁O₁₀PS
Molecular Weight:814.934
Hs Code.:

Synonyms:diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

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Chemical Property of diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

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Technology Process of diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

There total 1 articles about diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 6564-72-3
2,3,4,6-tetra-O-benzyl-D-glucopyranose

: 56069-39-7
diethyl phenylsulfonylmethylphosphonate

: 1193390-73-6
diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

Guidance literature:: With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine; In benzene; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.08.024

Reference yield: 96.0%

: 1193390-73-6
diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

: 1193390-84-9
diethyl ((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

Guidance literature:: With methanol; sodium dihydrogenphosphate; sodium amalgam; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.tet.2009.08.024

Reference yield: 91.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 1193390-73-6
diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate

: 1193390-93-0
(2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-(1-(phenylsulfonyl)vinyl)tetrahydro-2H-pyran

Guidance literature:: diethyl phenylsulfonyl((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)methylphosphonate; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.25h; Inert atmosphere;

formaldehyd; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.08.024